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1,3-Difurfurylbenzimidazolium chloride monohydrate

The title compound, C(17)H(15)N(2)O(2) (+)·Cl(−)·H(2)O, was synthesized from benzimidazole and furfryl chloride in dimethyl­formamide. The cationic benzimidazolium ring is connected to two furan rings via methyl­ene bridges. The furan rings make dihedral angle of 79.09 (18)° with respect to each oth...

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Detalles Bibliográficos
Autores principales: Akkurt, Mehmet, Şireci, Nihat, Deniz, Selma, Küçükbay, Hasan, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977341/
https://www.ncbi.nlm.nih.gov/pubmed/21583703
http://dx.doi.org/10.1107/S1600536809029626
Descripción
Sumario:The title compound, C(17)H(15)N(2)O(2) (+)·Cl(−)·H(2)O, was synthesized from benzimidazole and furfryl chloride in dimethyl­formamide. The cationic benzimidazolium ring is connected to two furan rings via methyl­ene bridges. The furan rings make dihedral angle of 79.09 (18)° with respect to each other, and make dihedral angles of 73.92 (12) and 72.58 (13)° with respect to the benzimidazole ring. O—H⋯Cl, C—H⋯O and C—H⋯Cl hydrogen bonds and C—H⋯π inter­actions contribute to the stabilization of the crystal structure. Furthermore, there is a π–π inter­action between adjacent five- and six-membered rings of the benzimidazole groups [centroid–centroid distance = 3.5305 (8) Å].