Cargando…
1,3-Difurfurylbenzimidazolium chloride monohydrate
The title compound, C(17)H(15)N(2)O(2) (+)·Cl(−)·H(2)O, was synthesized from benzimidazole and furfryl chloride in dimethylformamide. The cationic benzimidazolium ring is connected to two furan rings via methylene bridges. The furan rings make dihedral angle of 79.09 (18)° with respect to each oth...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977341/ https://www.ncbi.nlm.nih.gov/pubmed/21583703 http://dx.doi.org/10.1107/S1600536809029626 |
_version_ | 1782191084794806272 |
---|---|
author | Akkurt, Mehmet Şireci, Nihat Deniz, Selma Küçükbay, Hasan Büyükgüngör, Orhan |
author_facet | Akkurt, Mehmet Şireci, Nihat Deniz, Selma Küçükbay, Hasan Büyükgüngör, Orhan |
author_sort | Akkurt, Mehmet |
collection | PubMed |
description | The title compound, C(17)H(15)N(2)O(2) (+)·Cl(−)·H(2)O, was synthesized from benzimidazole and furfryl chloride in dimethylformamide. The cationic benzimidazolium ring is connected to two furan rings via methylene bridges. The furan rings make dihedral angle of 79.09 (18)° with respect to each other, and make dihedral angles of 73.92 (12) and 72.58 (13)° with respect to the benzimidazole ring. O—H⋯Cl, C—H⋯O and C—H⋯Cl hydrogen bonds and C—H⋯π interactions contribute to the stabilization of the crystal structure. Furthermore, there is a π–π interaction between adjacent five- and six-membered rings of the benzimidazole groups [centroid–centroid distance = 3.5305 (8) Å]. |
format | Text |
id | pubmed-2977341 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29773412010-12-30 1,3-Difurfurylbenzimidazolium chloride monohydrate Akkurt, Mehmet Şireci, Nihat Deniz, Selma Küçükbay, Hasan Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(15)N(2)O(2) (+)·Cl(−)·H(2)O, was synthesized from benzimidazole and furfryl chloride in dimethylformamide. The cationic benzimidazolium ring is connected to two furan rings via methylene bridges. The furan rings make dihedral angle of 79.09 (18)° with respect to each other, and make dihedral angles of 73.92 (12) and 72.58 (13)° with respect to the benzimidazole ring. O—H⋯Cl, C—H⋯O and C—H⋯Cl hydrogen bonds and C—H⋯π interactions contribute to the stabilization of the crystal structure. Furthermore, there is a π–π interaction between adjacent five- and six-membered rings of the benzimidazole groups [centroid–centroid distance = 3.5305 (8) Å]. International Union of Crystallography 2009-07-29 /pmc/articles/PMC2977341/ /pubmed/21583703 http://dx.doi.org/10.1107/S1600536809029626 Text en © Akkurt et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Akkurt, Mehmet Şireci, Nihat Deniz, Selma Küçükbay, Hasan Büyükgüngör, Orhan 1,3-Difurfurylbenzimidazolium chloride monohydrate |
title | 1,3-Difurfurylbenzimidazolium chloride monohydrate |
title_full | 1,3-Difurfurylbenzimidazolium chloride monohydrate |
title_fullStr | 1,3-Difurfurylbenzimidazolium chloride monohydrate |
title_full_unstemmed | 1,3-Difurfurylbenzimidazolium chloride monohydrate |
title_short | 1,3-Difurfurylbenzimidazolium chloride monohydrate |
title_sort | 1,3-difurfurylbenzimidazolium chloride monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977341/ https://www.ncbi.nlm.nih.gov/pubmed/21583703 http://dx.doi.org/10.1107/S1600536809029626 |
work_keys_str_mv | AT akkurtmehmet 13difurfurylbenzimidazoliumchloridemonohydrate AT sirecinihat 13difurfurylbenzimidazoliumchloridemonohydrate AT denizselma 13difurfurylbenzimidazoliumchloridemonohydrate AT kucukbayhasan 13difurfurylbenzimidazoliumchloridemonohydrate AT buyukgungororhan 13difurfurylbenzimidazoliumchloridemonohydrate |