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1,3-Difurfurylbenzimidazolium chloride monohydrate

The title compound, C(17)H(15)N(2)O(2) (+)·Cl(−)·H(2)O, was synthesized from benzimidazole and furfryl chloride in dimethyl­formamide. The cationic benzimidazolium ring is connected to two furan rings via methyl­ene bridges. The furan rings make dihedral angle of 79.09 (18)° with respect to each oth...

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Autores principales: Akkurt, Mehmet, Şireci, Nihat, Deniz, Selma, Küçükbay, Hasan, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977341/
https://www.ncbi.nlm.nih.gov/pubmed/21583703
http://dx.doi.org/10.1107/S1600536809029626
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author Akkurt, Mehmet
Şireci, Nihat
Deniz, Selma
Küçükbay, Hasan
Büyükgüngör, Orhan
author_facet Akkurt, Mehmet
Şireci, Nihat
Deniz, Selma
Küçükbay, Hasan
Büyükgüngör, Orhan
author_sort Akkurt, Mehmet
collection PubMed
description The title compound, C(17)H(15)N(2)O(2) (+)·Cl(−)·H(2)O, was synthesized from benzimidazole and furfryl chloride in dimethyl­formamide. The cationic benzimidazolium ring is connected to two furan rings via methyl­ene bridges. The furan rings make dihedral angle of 79.09 (18)° with respect to each other, and make dihedral angles of 73.92 (12) and 72.58 (13)° with respect to the benzimidazole ring. O—H⋯Cl, C—H⋯O and C—H⋯Cl hydrogen bonds and C—H⋯π inter­actions contribute to the stabilization of the crystal structure. Furthermore, there is a π–π inter­action between adjacent five- and six-membered rings of the benzimidazole groups [centroid–centroid distance = 3.5305 (8) Å].
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spelling pubmed-29773412010-12-30 1,3-Difurfurylbenzimidazolium chloride monohydrate Akkurt, Mehmet Şireci, Nihat Deniz, Selma Küçükbay, Hasan Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(15)N(2)O(2) (+)·Cl(−)·H(2)O, was synthesized from benzimidazole and furfryl chloride in dimethyl­formamide. The cationic benzimidazolium ring is connected to two furan rings via methyl­ene bridges. The furan rings make dihedral angle of 79.09 (18)° with respect to each other, and make dihedral angles of 73.92 (12) and 72.58 (13)° with respect to the benzimidazole ring. O—H⋯Cl, C—H⋯O and C—H⋯Cl hydrogen bonds and C—H⋯π inter­actions contribute to the stabilization of the crystal structure. Furthermore, there is a π–π inter­action between adjacent five- and six-membered rings of the benzimidazole groups [centroid–centroid distance = 3.5305 (8) Å]. International Union of Crystallography 2009-07-29 /pmc/articles/PMC2977341/ /pubmed/21583703 http://dx.doi.org/10.1107/S1600536809029626 Text en © Akkurt et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akkurt, Mehmet
Şireci, Nihat
Deniz, Selma
Küçükbay, Hasan
Büyükgüngör, Orhan
1,3-Difurfurylbenzimidazolium chloride monohydrate
title 1,3-Difurfurylbenzimidazolium chloride monohydrate
title_full 1,3-Difurfurylbenzimidazolium chloride monohydrate
title_fullStr 1,3-Difurfurylbenzimidazolium chloride monohydrate
title_full_unstemmed 1,3-Difurfurylbenzimidazolium chloride monohydrate
title_short 1,3-Difurfurylbenzimidazolium chloride monohydrate
title_sort 1,3-difurfurylbenzimidazolium chloride monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977341/
https://www.ncbi.nlm.nih.gov/pubmed/21583703
http://dx.doi.org/10.1107/S1600536809029626
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