Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) ethane-1,2-diol solvate

In the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(2)H(6)O(2), the coordination polyhedron around the Ni(2+) ion is a distorted octahedron, with four N atoms from two phenanthroline groups and two O atoms from a bidentate sulfate ligand. The Ni(2+) ion lies on a special position of site symmetry...

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Detalles Bibliográficos
Autores principales: Zhong, Kai-Long, Ni, Chao, Wang, Jian-Mei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977342/
https://www.ncbi.nlm.nih.gov/pubmed/21583369
http://dx.doi.org/10.1107/S1600536809026269
Descripción
Sumario:In the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(2)H(6)O(2), the coordination polyhedron around the Ni(2+) ion is a distorted octahedron, with four N atoms from two phenanthroline groups and two O atoms from a bidentate sulfate ligand. The Ni(2+) ion lies on a special position of site symmetry 2. Inter­molecular O—H⋯O hydrogen bonds help to stabilize the structure. The OH group of the ethane-1,2-diol solvent is disordered over two positions with equal occupancy.

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