Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) ethane-1,2-diol solvate

In the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(2)H(6)O(2), the coordination polyhedron around the Ni(2+) ion is a distorted octahedron, with four N atoms from two phenanthroline groups and two O atoms from a bidentate sulfate ligand. The Ni(2+) ion lies on a special position of site symmetry...

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Detalles Bibliográficos
Autores principales: Zhong, Kai-Long, Ni, Chao, Wang, Jian-Mei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977342/
https://www.ncbi.nlm.nih.gov/pubmed/21583369
http://dx.doi.org/10.1107/S1600536809026269
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author Zhong, Kai-Long
Ni, Chao
Wang, Jian-Mei
author_facet Zhong, Kai-Long
Ni, Chao
Wang, Jian-Mei
author_sort Zhong, Kai-Long
collection PubMed
description In the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(2)H(6)O(2), the coordination polyhedron around the Ni(2+) ion is a distorted octahedron, with four N atoms from two phenanthroline groups and two O atoms from a bidentate sulfate ligand. The Ni(2+) ion lies on a special position of site symmetry 2. Inter­molecular O—H⋯O hydrogen bonds help to stabilize the structure. The OH group of the ethane-1,2-diol solvent is disordered over two positions with equal occupancy.
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spelling pubmed-29773422010-12-30 Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) ethane-1,2-diol solvate Zhong, Kai-Long Ni, Chao Wang, Jian-Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(2)H(6)O(2), the coordination polyhedron around the Ni(2+) ion is a distorted octahedron, with four N atoms from two phenanthroline groups and two O atoms from a bidentate sulfate ligand. The Ni(2+) ion lies on a special position of site symmetry 2. Inter­molecular O—H⋯O hydrogen bonds help to stabilize the structure. The OH group of the ethane-1,2-diol solvent is disordered over two positions with equal occupancy. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977342/ /pubmed/21583369 http://dx.doi.org/10.1107/S1600536809026269 Text en © Zhong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhong, Kai-Long
Ni, Chao
Wang, Jian-Mei
Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) ethane-1,2-diol solvate
title Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) ethane-1,2-diol solvate
title_full Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) ethane-1,2-diol solvate
title_fullStr Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) ethane-1,2-diol solvate
title_full_unstemmed Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) ethane-1,2-diol solvate
title_short Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) ethane-1,2-diol solvate
title_sort bis(1,10-phenanthroline-κ(2) n,n′)(sulfato-κ(2) o,o′)nickel(ii) ethane-1,2-diol solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977342/
https://www.ncbi.nlm.nih.gov/pubmed/21583369
http://dx.doi.org/10.1107/S1600536809026269
work_keys_str_mv AT zhongkailong bis110phenanthrolinek2nnsulfatok2oonickeliiethane12diolsolvate
AT nichao bis110phenanthrolinek2nnsulfatok2oonickeliiethane12diolsolvate
AT wangjianmei bis110phenanthrolinek2nnsulfatok2oonickeliiethane12diolsolvate

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