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Bis(ethanol-κO)bis­(pyridine-3-carb­aldehyde-κN thio­semicarbazone)bis­(thio­cyanato-κN)iron(II)–pyridine-3-carbaldehyde thio­semicarbazone (1/2)

The crystal structure of the title Fe(II) complex, [Fe(NCS)(2)(C(7)H(8)N(4)S)(2)(CH(3)CH(2)OH)(2)]·2C(7)H(8)N(4)S, based on the Schiff base ligand pyridine-3-carbaldehyde thio­semicarbazone (pct), results from the cocrystallization of an Fe(II) coordination compound together with two of the pct liga...

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Detalles Bibliográficos
Autor principal: Wang, Shao-Mei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977344/
https://www.ncbi.nlm.nih.gov/pubmed/21583317
http://dx.doi.org/10.1107/S1600536809024076
Descripción
Sumario:The crystal structure of the title Fe(II) complex, [Fe(NCS)(2)(C(7)H(8)N(4)S)(2)(CH(3)CH(2)OH)(2)]·2C(7)H(8)N(4)S, based on the Schiff base ligand pyridine-3-carbaldehyde thio­semicarbazone (pct), results from the cocrystallization of an Fe(II) coordination compound together with two of the pct ligands. The complex unit is mononuclear, with the central Fe(II) ion located on a crystallographic centre of inversion and coordinated by four N atoms from two pct ligands and two thio­cyanate anions. The slightly distorted octa­hedral coordination is completed by two O atoms from ethanol mol­ecules. The crystal packing is accomplished inter­molecular N—H⋯S hydrogen bonds.