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Bis(ethanol-κO)bis(pyridine-3-carbaldehyde-κN thiosemicarbazone)bis(thiocyanato-κN)iron(II)–pyridine-3-carbaldehyde thiosemicarbazone (1/2)
The crystal structure of the title Fe(II) complex, [Fe(NCS)(2)(C(7)H(8)N(4)S)(2)(CH(3)CH(2)OH)(2)]·2C(7)H(8)N(4)S, based on the Schiff base ligand pyridine-3-carbaldehyde thiosemicarbazone (pct), results from the cocrystallization of an Fe(II) coordination compound together with two of the pct liga...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977344/ https://www.ncbi.nlm.nih.gov/pubmed/21583317 http://dx.doi.org/10.1107/S1600536809024076 |
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author | Wang, Shao-Mei |
author_facet | Wang, Shao-Mei |
author_sort | Wang, Shao-Mei |
collection | PubMed |
description | The crystal structure of the title Fe(II) complex, [Fe(NCS)(2)(C(7)H(8)N(4)S)(2)(CH(3)CH(2)OH)(2)]·2C(7)H(8)N(4)S, based on the Schiff base ligand pyridine-3-carbaldehyde thiosemicarbazone (pct), results from the cocrystallization of an Fe(II) coordination compound together with two of the pct ligands. The complex unit is mononuclear, with the central Fe(II) ion located on a crystallographic centre of inversion and coordinated by four N atoms from two pct ligands and two thiocyanate anions. The slightly distorted octahedral coordination is completed by two O atoms from ethanol molecules. The crystal packing is accomplished intermolecular N—H⋯S hydrogen bonds. |
format | Text |
id | pubmed-2977344 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29773442010-12-30 Bis(ethanol-κO)bis(pyridine-3-carbaldehyde-κN thiosemicarbazone)bis(thiocyanato-κN)iron(II)–pyridine-3-carbaldehyde thiosemicarbazone (1/2) Wang, Shao-Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title Fe(II) complex, [Fe(NCS)(2)(C(7)H(8)N(4)S)(2)(CH(3)CH(2)OH)(2)]·2C(7)H(8)N(4)S, based on the Schiff base ligand pyridine-3-carbaldehyde thiosemicarbazone (pct), results from the cocrystallization of an Fe(II) coordination compound together with two of the pct ligands. The complex unit is mononuclear, with the central Fe(II) ion located on a crystallographic centre of inversion and coordinated by four N atoms from two pct ligands and two thiocyanate anions. The slightly distorted octahedral coordination is completed by two O atoms from ethanol molecules. The crystal packing is accomplished intermolecular N—H⋯S hydrogen bonds. International Union of Crystallography 2009-07-01 /pmc/articles/PMC2977344/ /pubmed/21583317 http://dx.doi.org/10.1107/S1600536809024076 Text en © Shao-Mei Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Shao-Mei Bis(ethanol-κO)bis(pyridine-3-carbaldehyde-κN thiosemicarbazone)bis(thiocyanato-κN)iron(II)–pyridine-3-carbaldehyde thiosemicarbazone (1/2) |
title | Bis(ethanol-κO)bis(pyridine-3-carbaldehyde-κN thiosemicarbazone)bis(thiocyanato-κN)iron(II)–pyridine-3-carbaldehyde thiosemicarbazone (1/2) |
title_full | Bis(ethanol-κO)bis(pyridine-3-carbaldehyde-κN thiosemicarbazone)bis(thiocyanato-κN)iron(II)–pyridine-3-carbaldehyde thiosemicarbazone (1/2) |
title_fullStr | Bis(ethanol-κO)bis(pyridine-3-carbaldehyde-κN thiosemicarbazone)bis(thiocyanato-κN)iron(II)–pyridine-3-carbaldehyde thiosemicarbazone (1/2) |
title_full_unstemmed | Bis(ethanol-κO)bis(pyridine-3-carbaldehyde-κN thiosemicarbazone)bis(thiocyanato-κN)iron(II)–pyridine-3-carbaldehyde thiosemicarbazone (1/2) |
title_short | Bis(ethanol-κO)bis(pyridine-3-carbaldehyde-κN thiosemicarbazone)bis(thiocyanato-κN)iron(II)–pyridine-3-carbaldehyde thiosemicarbazone (1/2) |
title_sort | bis(ethanol-κo)bis(pyridine-3-carbaldehyde-κn thiosemicarbazone)bis(thiocyanato-κn)iron(ii)–pyridine-3-carbaldehyde thiosemicarbazone (1/2) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977344/ https://www.ncbi.nlm.nih.gov/pubmed/21583317 http://dx.doi.org/10.1107/S1600536809024076 |
work_keys_str_mv | AT wangshaomei bisethanolkobispyridine3carbaldehydeknthiosemicarbazonebisthiocyanatoknironiipyridine3carbaldehydethiosemicarbazone12 |