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Bis(ethanol-κO)bis­(pyridine-3-carb­aldehyde-κN thio­semicarbazone)bis­(thio­cyanato-κN)iron(II)–pyridine-3-carbaldehyde thio­semicarbazone (1/2)

The crystal structure of the title Fe(II) complex, [Fe(NCS)(2)(C(7)H(8)N(4)S)(2)(CH(3)CH(2)OH)(2)]·2C(7)H(8)N(4)S, based on the Schiff base ligand pyridine-3-carbaldehyde thio­semicarbazone (pct), results from the cocrystallization of an Fe(II) coordination compound together with two of the pct liga...

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Detalles Bibliográficos
Autor principal: Wang, Shao-Mei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977344/
https://www.ncbi.nlm.nih.gov/pubmed/21583317
http://dx.doi.org/10.1107/S1600536809024076
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author Wang, Shao-Mei
author_facet Wang, Shao-Mei
author_sort Wang, Shao-Mei
collection PubMed
description The crystal structure of the title Fe(II) complex, [Fe(NCS)(2)(C(7)H(8)N(4)S)(2)(CH(3)CH(2)OH)(2)]·2C(7)H(8)N(4)S, based on the Schiff base ligand pyridine-3-carbaldehyde thio­semicarbazone (pct), results from the cocrystallization of an Fe(II) coordination compound together with two of the pct ligands. The complex unit is mononuclear, with the central Fe(II) ion located on a crystallographic centre of inversion and coordinated by four N atoms from two pct ligands and two thio­cyanate anions. The slightly distorted octa­hedral coordination is completed by two O atoms from ethanol mol­ecules. The crystal packing is accomplished inter­molecular N—H⋯S hydrogen bonds.
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spelling pubmed-29773442010-12-30 Bis(ethanol-κO)bis­(pyridine-3-carb­aldehyde-κN thio­semicarbazone)bis­(thio­cyanato-κN)iron(II)–pyridine-3-carbaldehyde thio­semicarbazone (1/2) Wang, Shao-Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title Fe(II) complex, [Fe(NCS)(2)(C(7)H(8)N(4)S)(2)(CH(3)CH(2)OH)(2)]·2C(7)H(8)N(4)S, based on the Schiff base ligand pyridine-3-carbaldehyde thio­semicarbazone (pct), results from the cocrystallization of an Fe(II) coordination compound together with two of the pct ligands. The complex unit is mononuclear, with the central Fe(II) ion located on a crystallographic centre of inversion and coordinated by four N atoms from two pct ligands and two thio­cyanate anions. The slightly distorted octa­hedral coordination is completed by two O atoms from ethanol mol­ecules. The crystal packing is accomplished inter­molecular N—H⋯S hydrogen bonds. International Union of Crystallography 2009-07-01 /pmc/articles/PMC2977344/ /pubmed/21583317 http://dx.doi.org/10.1107/S1600536809024076 Text en © Shao-Mei Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Shao-Mei
Bis(ethanol-κO)bis­(pyridine-3-carb­aldehyde-κN thio­semicarbazone)bis­(thio­cyanato-κN)iron(II)–pyridine-3-carbaldehyde thio­semicarbazone (1/2)
title Bis(ethanol-κO)bis­(pyridine-3-carb­aldehyde-κN thio­semicarbazone)bis­(thio­cyanato-κN)iron(II)–pyridine-3-carbaldehyde thio­semicarbazone (1/2)
title_full Bis(ethanol-κO)bis­(pyridine-3-carb­aldehyde-κN thio­semicarbazone)bis­(thio­cyanato-κN)iron(II)–pyridine-3-carbaldehyde thio­semicarbazone (1/2)
title_fullStr Bis(ethanol-κO)bis­(pyridine-3-carb­aldehyde-κN thio­semicarbazone)bis­(thio­cyanato-κN)iron(II)–pyridine-3-carbaldehyde thio­semicarbazone (1/2)
title_full_unstemmed Bis(ethanol-κO)bis­(pyridine-3-carb­aldehyde-κN thio­semicarbazone)bis­(thio­cyanato-κN)iron(II)–pyridine-3-carbaldehyde thio­semicarbazone (1/2)
title_short Bis(ethanol-κO)bis­(pyridine-3-carb­aldehyde-κN thio­semicarbazone)bis­(thio­cyanato-κN)iron(II)–pyridine-3-carbaldehyde thio­semicarbazone (1/2)
title_sort bis(ethanol-κo)bis­(pyridine-3-carb­aldehyde-κn thio­semicarbazone)bis­(thio­cyanato-κn)iron(ii)–pyridine-3-carbaldehyde thio­semicarbazone (1/2)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977344/
https://www.ncbi.nlm.nih.gov/pubmed/21583317
http://dx.doi.org/10.1107/S1600536809024076
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