catena-Poly[[bis­[2-(1H-1,2,4-triazol-1-yl-κN (4))pyrazine]cadmium(II)]-di-μ-thio­cyanato-κ(2) S:N;κ(2) N:S]

The title compound, [Cd(NCS)(2)(C(6)H(5)N(5))(2)](n), is a coordination polymer with the Cd(II) centre located on a twofold rotation axis. The Cd(II) centre assumes a distorted octa­hedral geometry. The thio­cyanate anions function as bridging ligands between the Cd(II) centres, leading to a chain-l...

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Detalles Bibliográficos
Autores principales: Li, Hong, Xie, Long Miao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977348/
https://www.ncbi.nlm.nih.gov/pubmed/21583388
http://dx.doi.org/10.1107/S1600536809027135
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author Li, Hong
Xie, Long Miao
author_facet Li, Hong
Xie, Long Miao
author_sort Li, Hong
collection PubMed
description The title compound, [Cd(NCS)(2)(C(6)H(5)N(5))(2)](n), is a coordination polymer with the Cd(II) centre located on a twofold rotation axis. The Cd(II) centre assumes a distorted octa­hedral geometry. The thio­cyanate anions function as bridging ligands between the Cd(II) centres, leading to a chain-like arrangement expanding along [001].
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spelling pubmed-29773482010-12-30 catena-Poly[[bis­[2-(1H-1,2,4-triazol-1-yl-κN (4))pyrazine]cadmium(II)]-di-μ-thio­cyanato-κ(2) S:N;κ(2) N:S] Li, Hong Xie, Long Miao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(NCS)(2)(C(6)H(5)N(5))(2)](n), is a coordination polymer with the Cd(II) centre located on a twofold rotation axis. The Cd(II) centre assumes a distorted octa­hedral geometry. The thio­cyanate anions function as bridging ligands between the Cd(II) centres, leading to a chain-like arrangement expanding along [001]. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977348/ /pubmed/21583388 http://dx.doi.org/10.1107/S1600536809027135 Text en © Li and Xie 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Hong
Xie, Long Miao
catena-Poly[[bis­[2-(1H-1,2,4-triazol-1-yl-κN (4))pyrazine]cadmium(II)]-di-μ-thio­cyanato-κ(2) S:N;κ(2) N:S]
title catena-Poly[[bis­[2-(1H-1,2,4-triazol-1-yl-κN (4))pyrazine]cadmium(II)]-di-μ-thio­cyanato-κ(2) S:N;κ(2) N:S]
title_full catena-Poly[[bis­[2-(1H-1,2,4-triazol-1-yl-κN (4))pyrazine]cadmium(II)]-di-μ-thio­cyanato-κ(2) S:N;κ(2) N:S]
title_fullStr catena-Poly[[bis­[2-(1H-1,2,4-triazol-1-yl-κN (4))pyrazine]cadmium(II)]-di-μ-thio­cyanato-κ(2) S:N;κ(2) N:S]
title_full_unstemmed catena-Poly[[bis­[2-(1H-1,2,4-triazol-1-yl-κN (4))pyrazine]cadmium(II)]-di-μ-thio­cyanato-κ(2) S:N;κ(2) N:S]
title_short catena-Poly[[bis­[2-(1H-1,2,4-triazol-1-yl-κN (4))pyrazine]cadmium(II)]-di-μ-thio­cyanato-κ(2) S:N;κ(2) N:S]
title_sort catena-poly[[bis­[2-(1h-1,2,4-triazol-1-yl-κn (4))pyrazine]cadmium(ii)]-di-μ-thio­cyanato-κ(2) s:n;κ(2) n:s]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977348/
https://www.ncbi.nlm.nih.gov/pubmed/21583388
http://dx.doi.org/10.1107/S1600536809027135
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AT xielongmiao catenapolybis21h124triazol1ylkn4pyrazinecadmiumiidimthiocyanatok2snk2ns

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