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2-Methyl-4-oxopentan-2-aminium 2-sulfamoylbenzoate

In the title salt, C(6)H(14)NO(+)·C(7)H(6)NO(4)S(−), the 2-sulfamoylbenzoate anion has two intra­molecular hydrogen bonds, forming a five membered C—H⋯O and a seven-membered N—H⋯O twisted ring with ring motifs S(5) and S(7), respectively, while the 2-methyl-4-oxopentan-2-aminium cation also has a st...

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Detalles Bibliográficos
Autores principales: Rafique, Muhammad, Hussain, Ghulam, Siddiqui, Waseeq Ahmad, Tahir, M. Nawaz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977349/
https://www.ncbi.nlm.nih.gov/pubmed/21583576
http://dx.doi.org/10.1107/S1600536809027007
Descripción
Sumario:In the title salt, C(6)H(14)NO(+)·C(7)H(6)NO(4)S(−), the 2-sulfamoylbenzoate anion has two intra­molecular hydrogen bonds, forming a five membered C—H⋯O and a seven-membered N—H⋯O twisted ring with ring motifs S(5) and S(7), respectively, while the 2-methyl-4-oxopentan-2-aminium cation also has a stabilizing intra­molecular N—H⋯O hydrogen bond with a twisted S(6) ring motif. The anions form inversion-related dimers with R (2) (2)(8) ring motifs through inter­molecular N—H⋯O hydrogen bonding. The dimers and cations are further linked and stabilized through inter­molecular N—H⋯O and C—H⋯O bonds, forming zigzag-shaped layers that extend along the crystallographic a axis.