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2-Methyl-4-oxopentan-2-aminium 2-sulfamoylbenzoate
In the title salt, C(6)H(14)NO(+)·C(7)H(6)NO(4)S(−), the 2-sulfamoylbenzoate anion has two intramolecular hydrogen bonds, forming a five membered C—H⋯O and a seven-membered N—H⋯O twisted ring with ring motifs S(5) and S(7), respectively, while the 2-methyl-4-oxopentan-2-aminium cation also has a st...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977349/ https://www.ncbi.nlm.nih.gov/pubmed/21583576 http://dx.doi.org/10.1107/S1600536809027007 |
Sumario: | In the title salt, C(6)H(14)NO(+)·C(7)H(6)NO(4)S(−), the 2-sulfamoylbenzoate anion has two intramolecular hydrogen bonds, forming a five membered C—H⋯O and a seven-membered N—H⋯O twisted ring with ring motifs S(5) and S(7), respectively, while the 2-methyl-4-oxopentan-2-aminium cation also has a stabilizing intramolecular N—H⋯O hydrogen bond with a twisted S(6) ring motif. The anions form inversion-related dimers with R (2) (2)(8) ring motifs through intermolecular N—H⋯O hydrogen bonding. The dimers and cations are further linked and stabilized through intermolecular N—H⋯O and C—H⋯O bonds, forming zigzag-shaped layers that extend along the crystallographic a axis. |
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