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2-Methyl-4-oxopentan-2-aminium 2-sulfamoylbenzoate

In the title salt, C(6)H(14)NO(+)·C(7)H(6)NO(4)S(−), the 2-sulfamoylbenzoate anion has two intra­molecular hydrogen bonds, forming a five membered C—H⋯O and a seven-membered N—H⋯O twisted ring with ring motifs S(5) and S(7), respectively, while the 2-methyl-4-oxopentan-2-aminium cation also has a st...

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Detalles Bibliográficos
Autores principales: Rafique, Muhammad, Hussain, Ghulam, Siddiqui, Waseeq Ahmad, Tahir, M. Nawaz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977349/
https://www.ncbi.nlm.nih.gov/pubmed/21583576
http://dx.doi.org/10.1107/S1600536809027007
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author Rafique, Muhammad
Hussain, Ghulam
Siddiqui, Waseeq Ahmad
Tahir, M. Nawaz
author_facet Rafique, Muhammad
Hussain, Ghulam
Siddiqui, Waseeq Ahmad
Tahir, M. Nawaz
author_sort Rafique, Muhammad
collection PubMed
description In the title salt, C(6)H(14)NO(+)·C(7)H(6)NO(4)S(−), the 2-sulfamoylbenzoate anion has two intra­molecular hydrogen bonds, forming a five membered C—H⋯O and a seven-membered N—H⋯O twisted ring with ring motifs S(5) and S(7), respectively, while the 2-methyl-4-oxopentan-2-aminium cation also has a stabilizing intra­molecular N—H⋯O hydrogen bond with a twisted S(6) ring motif. The anions form inversion-related dimers with R (2) (2)(8) ring motifs through inter­molecular N—H⋯O hydrogen bonding. The dimers and cations are further linked and stabilized through inter­molecular N—H⋯O and C—H⋯O bonds, forming zigzag-shaped layers that extend along the crystallographic a axis.
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spelling pubmed-29773492010-12-30 2-Methyl-4-oxopentan-2-aminium 2-sulfamoylbenzoate Rafique, Muhammad Hussain, Ghulam Siddiqui, Waseeq Ahmad Tahir, M. Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(6)H(14)NO(+)·C(7)H(6)NO(4)S(−), the 2-sulfamoylbenzoate anion has two intra­molecular hydrogen bonds, forming a five membered C—H⋯O and a seven-membered N—H⋯O twisted ring with ring motifs S(5) and S(7), respectively, while the 2-methyl-4-oxopentan-2-aminium cation also has a stabilizing intra­molecular N—H⋯O hydrogen bond with a twisted S(6) ring motif. The anions form inversion-related dimers with R (2) (2)(8) ring motifs through inter­molecular N—H⋯O hydrogen bonding. The dimers and cations are further linked and stabilized through inter­molecular N—H⋯O and C—H⋯O bonds, forming zigzag-shaped layers that extend along the crystallographic a axis. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977349/ /pubmed/21583576 http://dx.doi.org/10.1107/S1600536809027007 Text en © Rafique et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rafique, Muhammad
Hussain, Ghulam
Siddiqui, Waseeq Ahmad
Tahir, M. Nawaz
2-Methyl-4-oxopentan-2-aminium 2-sulfamoylbenzoate
title 2-Methyl-4-oxopentan-2-aminium 2-sulfamoylbenzoate
title_full 2-Methyl-4-oxopentan-2-aminium 2-sulfamoylbenzoate
title_fullStr 2-Methyl-4-oxopentan-2-aminium 2-sulfamoylbenzoate
title_full_unstemmed 2-Methyl-4-oxopentan-2-aminium 2-sulfamoylbenzoate
title_short 2-Methyl-4-oxopentan-2-aminium 2-sulfamoylbenzoate
title_sort 2-methyl-4-oxopentan-2-aminium 2-sulfamoylbenzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977349/
https://www.ncbi.nlm.nih.gov/pubmed/21583576
http://dx.doi.org/10.1107/S1600536809027007
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