2-Bromo-N-(2-chloro­phen­yl)acetamide

The conformation of the N—H bond in the structure of the title compound, C(8)H(7)BrClNO, is syn to the 2-chloro substituent in the aniline ring and anti to both the C=O and C—Br bonds in the side chain, similar to that observed in 2-chloro-N-(2-chloro­phen­yl)acetamide. In the crystal, mol­ecules ar...

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Autores principales: Gowda, B. Thimme, Foro, Sabine, Suchetan, P. A., Fuess, Hartmut, Terao, Hiromitsu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977351/
https://www.ncbi.nlm.nih.gov/pubmed/21583670
http://dx.doi.org/10.1107/S1600536809028918
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author Gowda, B. Thimme
Foro, Sabine
Suchetan, P. A.
Fuess, Hartmut
Terao, Hiromitsu
author_facet Gowda, B. Thimme
Foro, Sabine
Suchetan, P. A.
Fuess, Hartmut
Terao, Hiromitsu
author_sort Gowda, B. Thimme
collection PubMed
description The conformation of the N—H bond in the structure of the title compound, C(8)H(7)BrClNO, is syn to the 2-chloro substituent in the aniline ring and anti to both the C=O and C—Br bonds in the side chain, similar to that observed in 2-chloro-N-(2-chloro­phen­yl)acetamide. In the crystal, mol­ecules are linked into chains along the a axis by N—H⋯O hydrogen bonds. These chains are in turn linked into pairs, in the form of columns, through much weaker C—H⋯Cl and Br⋯Br [4.3027 (3) Å] inter­actions.
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spelling pubmed-29773512010-12-30 2-Bromo-N-(2-chloro­phen­yl)acetamide Gowda, B. Thimme Foro, Sabine Suchetan, P. A. Fuess, Hartmut Terao, Hiromitsu Acta Crystallogr Sect E Struct Rep Online Organic Papers The conformation of the N—H bond in the structure of the title compound, C(8)H(7)BrClNO, is syn to the 2-chloro substituent in the aniline ring and anti to both the C=O and C—Br bonds in the side chain, similar to that observed in 2-chloro-N-(2-chloro­phen­yl)acetamide. In the crystal, mol­ecules are linked into chains along the a axis by N—H⋯O hydrogen bonds. These chains are in turn linked into pairs, in the form of columns, through much weaker C—H⋯Cl and Br⋯Br [4.3027 (3) Å] inter­actions. International Union of Crystallography 2009-07-25 /pmc/articles/PMC2977351/ /pubmed/21583670 http://dx.doi.org/10.1107/S1600536809028918 Text en © Gowda et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Suchetan, P. A.
Fuess, Hartmut
Terao, Hiromitsu
2-Bromo-N-(2-chloro­phen­yl)acetamide
title 2-Bromo-N-(2-chloro­phen­yl)acetamide
title_full 2-Bromo-N-(2-chloro­phen­yl)acetamide
title_fullStr 2-Bromo-N-(2-chloro­phen­yl)acetamide
title_full_unstemmed 2-Bromo-N-(2-chloro­phen­yl)acetamide
title_short 2-Bromo-N-(2-chloro­phen­yl)acetamide
title_sort 2-bromo-n-(2-chloro­phen­yl)acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977351/
https://www.ncbi.nlm.nih.gov/pubmed/21583670
http://dx.doi.org/10.1107/S1600536809028918
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AT forosabine 2bromon2chlorophenylacetamide
AT suchetanpa 2bromon2chlorophenylacetamide
AT fuesshartmut 2bromon2chlorophenylacetamide
AT teraohiromitsu 2bromon2chlorophenylacetamide

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