Bis(μ(2)-3,5-diisopropyl-4H-1,2,4-triazole-κ(2) N (1):N (2))bis­[(nitrato-κO)silver(I)]

The neutral N-heterocycle in the title centrosymmetric dinuclear compound, [Ag(2)(NO(3))(2)(C(8)H(15)N(3))(2)], bridges two metal atoms through its imino N atoms. The N—Ag—N skeleton is bent [N—Ag—N = 127.2 (3)°]; as one of two O atoms of the nitrate anion is nearly coplanar with this N—Ag—N skeleto...

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Detalles Bibliográficos
Autores principales: Wang, Zhao-Yang, Wang, Ying-Li, Yang, Guang, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977357/
https://www.ncbi.nlm.nih.gov/pubmed/21583418
http://dx.doi.org/10.1107/S1600536809028384
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author Wang, Zhao-Yang
Wang, Ying-Li
Yang, Guang
Ng, Seik Weng
author_facet Wang, Zhao-Yang
Wang, Ying-Li
Yang, Guang
Ng, Seik Weng
author_sort Wang, Zhao-Yang
collection PubMed
description The neutral N-heterocycle in the title centrosymmetric dinuclear compound, [Ag(2)(NO(3))(2)(C(8)H(15)N(3))(2)], bridges two metal atoms through its imino N atoms. The N—Ag—N skeleton is bent [N—Ag—N = 127.2 (3)°]; as one of two O atoms of the nitrate anion is nearly coplanar with this N—Ag—N skeleton [Ag—O = 2.63 (1) Å], the coordination geometry around the Ag(I) atom is regarded as trigonal-planar. One of the two isopropyl groups is disordered over two positions in respect of the methyl groups in a 1:1 ratio. In the crystal structure, inter­molecular N—H⋯O hydrogen bonding is observed between the nitrate groups and triazole ligands.
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spelling pubmed-29773572010-12-30 Bis(μ(2)-3,5-diisopropyl-4H-1,2,4-triazole-κ(2) N (1):N (2))bis­[(nitrato-κO)silver(I)] Wang, Zhao-Yang Wang, Ying-Li Yang, Guang Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The neutral N-heterocycle in the title centrosymmetric dinuclear compound, [Ag(2)(NO(3))(2)(C(8)H(15)N(3))(2)], bridges two metal atoms through its imino N atoms. The N—Ag—N skeleton is bent [N—Ag—N = 127.2 (3)°]; as one of two O atoms of the nitrate anion is nearly coplanar with this N—Ag—N skeleton [Ag—O = 2.63 (1) Å], the coordination geometry around the Ag(I) atom is regarded as trigonal-planar. One of the two isopropyl groups is disordered over two positions in respect of the methyl groups in a 1:1 ratio. In the crystal structure, inter­molecular N—H⋯O hydrogen bonding is observed between the nitrate groups and triazole ligands. International Union of Crystallography 2009-07-22 /pmc/articles/PMC2977357/ /pubmed/21583418 http://dx.doi.org/10.1107/S1600536809028384 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Zhao-Yang
Wang, Ying-Li
Yang, Guang
Ng, Seik Weng
Bis(μ(2)-3,5-diisopropyl-4H-1,2,4-triazole-κ(2) N (1):N (2))bis­[(nitrato-κO)silver(I)]
title Bis(μ(2)-3,5-diisopropyl-4H-1,2,4-triazole-κ(2) N (1):N (2))bis­[(nitrato-κO)silver(I)]
title_full Bis(μ(2)-3,5-diisopropyl-4H-1,2,4-triazole-κ(2) N (1):N (2))bis­[(nitrato-κO)silver(I)]
title_fullStr Bis(μ(2)-3,5-diisopropyl-4H-1,2,4-triazole-κ(2) N (1):N (2))bis­[(nitrato-κO)silver(I)]
title_full_unstemmed Bis(μ(2)-3,5-diisopropyl-4H-1,2,4-triazole-κ(2) N (1):N (2))bis­[(nitrato-κO)silver(I)]
title_short Bis(μ(2)-3,5-diisopropyl-4H-1,2,4-triazole-κ(2) N (1):N (2))bis­[(nitrato-κO)silver(I)]
title_sort bis(μ(2)-3,5-diisopropyl-4h-1,2,4-triazole-κ(2) n (1):n (2))bis­[(nitrato-κo)silver(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977357/
https://www.ncbi.nlm.nih.gov/pubmed/21583418
http://dx.doi.org/10.1107/S1600536809028384
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