Cargando…
2,3-Diaminopyridinium 3-aminobenzoate
In the title salt, C(5)H(8)N(3) (+)·C(7)H(6)NO(2) (−), the pyridine N atom of the 2,3-diaminopyridine molecule is protonated. The protonated N atom and one of the two N atoms of the 2-amino groups are hydrogen bonded to the 3-aminobenzoate anion through a pair of N—H⋯O hydrogen bonds, forming an...
Autores principales: | , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977358/ https://www.ncbi.nlm.nih.gov/pubmed/21583446 http://dx.doi.org/10.1107/S1600536809024362 |
_version_ | 1782191088884252672 |
---|---|
author | Balasubramani, Kasthuri Fun, Hoong-Kun |
author_facet | Balasubramani, Kasthuri Fun, Hoong-Kun |
author_sort | Balasubramani, Kasthuri |
collection | PubMed |
description | In the title salt, C(5)H(8)N(3) (+)·C(7)H(6)NO(2) (−), the pyridine N atom of the 2,3-diaminopyridine molecule is protonated. The protonated N atom and one of the two N atoms of the 2-amino groups are hydrogen bonded to the 3-aminobenzoate anion through a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The carboxylate mean plane of the 3-aminobenzoate anion is twisted by 8.81 (7)° from the attached ring. The crystal structure is further stabilized by π–π interactions [centroid–centroid distance 3.6827 (7) Å]. |
format | Text |
id | pubmed-2977358 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29773582010-12-30 2,3-Diaminopyridinium 3-aminobenzoate Balasubramani, Kasthuri Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(5)H(8)N(3) (+)·C(7)H(6)NO(2) (−), the pyridine N atom of the 2,3-diaminopyridine molecule is protonated. The protonated N atom and one of the two N atoms of the 2-amino groups are hydrogen bonded to the 3-aminobenzoate anion through a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The carboxylate mean plane of the 3-aminobenzoate anion is twisted by 8.81 (7)° from the attached ring. The crystal structure is further stabilized by π–π interactions [centroid–centroid distance 3.6827 (7) Å]. International Union of Crystallography 2009-07-01 /pmc/articles/PMC2977358/ /pubmed/21583446 http://dx.doi.org/10.1107/S1600536809024362 Text en © Balasubramani and Fun 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Balasubramani, Kasthuri Fun, Hoong-Kun 2,3-Diaminopyridinium 3-aminobenzoate |
title | 2,3-Diaminopyridinium 3-aminobenzoate |
title_full | 2,3-Diaminopyridinium 3-aminobenzoate |
title_fullStr | 2,3-Diaminopyridinium 3-aminobenzoate |
title_full_unstemmed | 2,3-Diaminopyridinium 3-aminobenzoate |
title_short | 2,3-Diaminopyridinium 3-aminobenzoate |
title_sort | 2,3-diaminopyridinium 3-aminobenzoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977358/ https://www.ncbi.nlm.nih.gov/pubmed/21583446 http://dx.doi.org/10.1107/S1600536809024362 |
work_keys_str_mv | AT balasubramanikasthuri 23diaminopyridinium3aminobenzoate AT funhoongkun 23diaminopyridinium3aminobenzoate |