Triaqua­dichlorido[5-(4-pyridinio)tetra­zolato-κN (2)]cobalt(II) monohydrate

The title compound, [CoCl(2)(C(6)H(5)N(5))(H(2)O)(3)]·H(2)O, was synthesized by hydro­thermal reaction of CoCl(2) with 4-(2H-tetra­zol-5-yl)pyridine. The Co(II) cation is coordinated by two Cl(−) ions, one N atom from the 5-(4-pyridinio)tetra­zolate zwitterion and three O atoms from three water mol­...

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Detalles Bibliográficos
Autor principal: Wang, Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977361/
https://www.ncbi.nlm.nih.gov/pubmed/21583322
http://dx.doi.org/10.1107/S1600536809024337
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author Wang, Bo
author_facet Wang, Bo
author_sort Wang, Bo
collection PubMed
description The title compound, [CoCl(2)(C(6)H(5)N(5))(H(2)O)(3)]·H(2)O, was synthesized by hydro­thermal reaction of CoCl(2) with 4-(2H-tetra­zol-5-yl)pyridine. The Co(II) cation is coordinated by two Cl(−) ions, one N atom from the 5-(4-pyridinio)tetra­zolate zwitterion and three O atoms from three water mol­ecules in a distorted octa­hedral geometry. In the crystal, mol­ecules are linked into a three-dimensional network by N—H⋯Cl hydrogen bonds and O—H⋯O/N/Cl hydrogen bonds involv­ing both coordinated and uncoordinated water mol­ecules. Strong π–π stacking is present between parallel pyridinium and tetra­zolate rings [centroid–centroid distances = 3.411 (2) and 3.436 (2) Å].
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spelling pubmed-29773612010-12-30 Triaqua­dichlorido[5-(4-pyridinio)tetra­zolato-κN (2)]cobalt(II) monohydrate Wang, Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [CoCl(2)(C(6)H(5)N(5))(H(2)O)(3)]·H(2)O, was synthesized by hydro­thermal reaction of CoCl(2) with 4-(2H-tetra­zol-5-yl)pyridine. The Co(II) cation is coordinated by two Cl(−) ions, one N atom from the 5-(4-pyridinio)tetra­zolate zwitterion and three O atoms from three water mol­ecules in a distorted octa­hedral geometry. In the crystal, mol­ecules are linked into a three-dimensional network by N—H⋯Cl hydrogen bonds and O—H⋯O/N/Cl hydrogen bonds involv­ing both coordinated and uncoordinated water mol­ecules. Strong π–π stacking is present between parallel pyridinium and tetra­zolate rings [centroid–centroid distances = 3.411 (2) and 3.436 (2) Å]. International Union of Crystallography 2009-07-01 /pmc/articles/PMC2977361/ /pubmed/21583322 http://dx.doi.org/10.1107/S1600536809024337 Text en © Bo Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Bo
Triaqua­dichlorido[5-(4-pyridinio)tetra­zolato-κN (2)]cobalt(II) monohydrate
title Triaqua­dichlorido[5-(4-pyridinio)tetra­zolato-κN (2)]cobalt(II) monohydrate
title_full Triaqua­dichlorido[5-(4-pyridinio)tetra­zolato-κN (2)]cobalt(II) monohydrate
title_fullStr Triaqua­dichlorido[5-(4-pyridinio)tetra­zolato-κN (2)]cobalt(II) monohydrate
title_full_unstemmed Triaqua­dichlorido[5-(4-pyridinio)tetra­zolato-κN (2)]cobalt(II) monohydrate
title_short Triaqua­dichlorido[5-(4-pyridinio)tetra­zolato-κN (2)]cobalt(II) monohydrate
title_sort triaqua­dichlorido[5-(4-pyridinio)tetra­zolato-κn (2)]cobalt(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977361/
https://www.ncbi.nlm.nih.gov/pubmed/21583322
http://dx.doi.org/10.1107/S1600536809024337
work_keys_str_mv AT wangbo triaquadichlorido54pyridiniotetrazolatokn2cobaltiimonohydrate

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