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Dichlorido(2,9-diethoxy-1,10-phenanthroline-κ(2) N,N′)zinc(II)
All non-H atoms except for the Cl atoms lie on a mirror plane in the title complex, [ZnCl(2)(C(16)H(16)N(2)O(2))]. The Zn(II) ion is coordinated by two N atoms from a bis-chelating 2,9-diethoxy-1,10-phenanthroline ligand and two symmetry-related Cl atoms in a distorted tetrahedral environment. The...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977366/ https://www.ncbi.nlm.nih.gov/pubmed/21583328 http://dx.doi.org/10.1107/S1600536809024490 |
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author | Niu, Cao-Yuan Dang, Yu-Li Wan, Xin-Sheng Kou, Chun-Hong |
author_facet | Niu, Cao-Yuan Dang, Yu-Li Wan, Xin-Sheng Kou, Chun-Hong |
author_sort | Niu, Cao-Yuan |
collection | PubMed |
description | All non-H atoms except for the Cl atoms lie on a mirror plane in the title complex, [ZnCl(2)(C(16)H(16)N(2)O(2))]. The Zn(II) ion is coordinated by two N atoms from a bis-chelating 2,9-diethoxy-1,10-phenanthroline ligand and two symmetry-related Cl atoms in a distorted tetrahedral environment. The two Zn—N bond lengths are significantly different from each other and the N—Zn—N angle is acute. In the crystal structure, there are weak but significant π–π stacking interactions between phenanthroline rings, with a centroid–centroid distance of 3.764 (1) Å. |
format | Text |
id | pubmed-2977366 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29773662010-12-30 Dichlorido(2,9-diethoxy-1,10-phenanthroline-κ(2) N,N′)zinc(II) Niu, Cao-Yuan Dang, Yu-Li Wan, Xin-Sheng Kou, Chun-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers All non-H atoms except for the Cl atoms lie on a mirror plane in the title complex, [ZnCl(2)(C(16)H(16)N(2)O(2))]. The Zn(II) ion is coordinated by two N atoms from a bis-chelating 2,9-diethoxy-1,10-phenanthroline ligand and two symmetry-related Cl atoms in a distorted tetrahedral environment. The two Zn—N bond lengths are significantly different from each other and the N—Zn—N angle is acute. In the crystal structure, there are weak but significant π–π stacking interactions between phenanthroline rings, with a centroid–centroid distance of 3.764 (1) Å. International Union of Crystallography 2009-07-01 /pmc/articles/PMC2977366/ /pubmed/21583328 http://dx.doi.org/10.1107/S1600536809024490 Text en © Niu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Niu, Cao-Yuan Dang, Yu-Li Wan, Xin-Sheng Kou, Chun-Hong Dichlorido(2,9-diethoxy-1,10-phenanthroline-κ(2) N,N′)zinc(II) |
title | Dichlorido(2,9-diethoxy-1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
title_full | Dichlorido(2,9-diethoxy-1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
title_fullStr | Dichlorido(2,9-diethoxy-1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
title_full_unstemmed | Dichlorido(2,9-diethoxy-1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
title_short | Dichlorido(2,9-diethoxy-1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
title_sort | dichlorido(2,9-diethoxy-1,10-phenanthroline-κ(2)
n,n′)zinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977366/ https://www.ncbi.nlm.nih.gov/pubmed/21583328 http://dx.doi.org/10.1107/S1600536809024490 |
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