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Dichlorido(2,9-dieth­oxy-1,10-phenanthroline-κ(2) N,N′)zinc(II)

All non-H atoms except for the Cl atoms lie on a mirror plane in the title complex, [ZnCl(2)(C(16)H(16)N(2)O(2))]. The Zn(II) ion is coordinated by two N atoms from a bis-chelating 2,9-dieth­oxy-1,10-phenanthroline ligand and two symmetry-related Cl atoms in a distorted tetra­hedral environment. The...

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Detalles Bibliográficos
Autores principales: Niu, Cao-Yuan, Dang, Yu-Li, Wan, Xin-Sheng, Kou, Chun-Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977366/
https://www.ncbi.nlm.nih.gov/pubmed/21583328
http://dx.doi.org/10.1107/S1600536809024490
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author Niu, Cao-Yuan
Dang, Yu-Li
Wan, Xin-Sheng
Kou, Chun-Hong
author_facet Niu, Cao-Yuan
Dang, Yu-Li
Wan, Xin-Sheng
Kou, Chun-Hong
author_sort Niu, Cao-Yuan
collection PubMed
description All non-H atoms except for the Cl atoms lie on a mirror plane in the title complex, [ZnCl(2)(C(16)H(16)N(2)O(2))]. The Zn(II) ion is coordinated by two N atoms from a bis-chelating 2,9-dieth­oxy-1,10-phenanthroline ligand and two symmetry-related Cl atoms in a distorted tetra­hedral environment. The two Zn—N bond lengths are significantly different from each other and the N—Zn—N angle is acute. In the crystal structure, there are weak but significant π–π stacking inter­actions between phenanthroline rings, with a centroid–centroid distance of 3.764 (1) Å.
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spelling pubmed-29773662010-12-30 Dichlorido(2,9-dieth­oxy-1,10-phenanthroline-κ(2) N,N′)zinc(II) Niu, Cao-Yuan Dang, Yu-Li Wan, Xin-Sheng Kou, Chun-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers All non-H atoms except for the Cl atoms lie on a mirror plane in the title complex, [ZnCl(2)(C(16)H(16)N(2)O(2))]. The Zn(II) ion is coordinated by two N atoms from a bis-chelating 2,9-dieth­oxy-1,10-phenanthroline ligand and two symmetry-related Cl atoms in a distorted tetra­hedral environment. The two Zn—N bond lengths are significantly different from each other and the N—Zn—N angle is acute. In the crystal structure, there are weak but significant π–π stacking inter­actions between phenanthroline rings, with a centroid–centroid distance of 3.764 (1) Å. International Union of Crystallography 2009-07-01 /pmc/articles/PMC2977366/ /pubmed/21583328 http://dx.doi.org/10.1107/S1600536809024490 Text en © Niu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Niu, Cao-Yuan
Dang, Yu-Li
Wan, Xin-Sheng
Kou, Chun-Hong
Dichlorido(2,9-dieth­oxy-1,10-phenanthroline-κ(2) N,N′)zinc(II)
title Dichlorido(2,9-dieth­oxy-1,10-phenanthroline-κ(2) N,N′)zinc(II)
title_full Dichlorido(2,9-dieth­oxy-1,10-phenanthroline-κ(2) N,N′)zinc(II)
title_fullStr Dichlorido(2,9-dieth­oxy-1,10-phenanthroline-κ(2) N,N′)zinc(II)
title_full_unstemmed Dichlorido(2,9-dieth­oxy-1,10-phenanthroline-κ(2) N,N′)zinc(II)
title_short Dichlorido(2,9-dieth­oxy-1,10-phenanthroline-κ(2) N,N′)zinc(II)
title_sort dichlorido(2,9-dieth­oxy-1,10-phenanthroline-κ(2) n,n′)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977366/
https://www.ncbi.nlm.nih.gov/pubmed/21583328
http://dx.doi.org/10.1107/S1600536809024490
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