2-{5-[N-(2-Pyridyl)carbamo­yl]pentan­amido}pyridinium hexa­fluoro­phosphate

In the crystal structure of the title compound, C(16)H(19)N(4)O(2) (+)·PF(6) (−), the cations and anions are situated on centres of inversion. Thus, the N—H H atom is disordered over both N atoms due to symmetry. In the crystal, mol­ecules are connected via N—H⋯F and N—H⋯O hydrogen bonds. The cation...

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Autores principales: Cheng, Pei-Chi, Wu, Chia-Jun, Chen, Huan-Ching, Chen, Jhy-Der, Wang, Ju-Chun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977368/
https://www.ncbi.nlm.nih.gov/pubmed/21583527
http://dx.doi.org/10.1107/S1600536809026488
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author Cheng, Pei-Chi
Wu, Chia-Jun
Chen, Huan-Ching
Chen, Jhy-Der
Wang, Ju-Chun
author_facet Cheng, Pei-Chi
Wu, Chia-Jun
Chen, Huan-Ching
Chen, Jhy-Der
Wang, Ju-Chun
author_sort Cheng, Pei-Chi
collection PubMed
description In the crystal structure of the title compound, C(16)H(19)N(4)O(2) (+)·PF(6) (−), the cations and anions are situated on centres of inversion. Thus, the N—H H atom is disordered over both N atoms due to symmetry. In the crystal, mol­ecules are connected via N—H⋯F and N—H⋯O hydrogen bonds. The cation adopts the ⋯AAA⋯ trans conformation in the solid state.
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spelling pubmed-29773682010-12-30 2-{5-[N-(2-Pyridyl)carbamo­yl]pentan­amido}pyridinium hexa­fluoro­phosphate Cheng, Pei-Chi Wu, Chia-Jun Chen, Huan-Ching Chen, Jhy-Der Wang, Ju-Chun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(16)H(19)N(4)O(2) (+)·PF(6) (−), the cations and anions are situated on centres of inversion. Thus, the N—H H atom is disordered over both N atoms due to symmetry. In the crystal, mol­ecules are connected via N—H⋯F and N—H⋯O hydrogen bonds. The cation adopts the ⋯AAA⋯ trans conformation in the solid state. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977368/ /pubmed/21583527 http://dx.doi.org/10.1107/S1600536809026488 Text en © Cheng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cheng, Pei-Chi
Wu, Chia-Jun
Chen, Huan-Ching
Chen, Jhy-Der
Wang, Ju-Chun
2-{5-[N-(2-Pyridyl)carbamo­yl]pentan­amido}pyridinium hexa­fluoro­phosphate
title 2-{5-[N-(2-Pyridyl)carbamo­yl]pentan­amido}pyridinium hexa­fluoro­phosphate
title_full 2-{5-[N-(2-Pyridyl)carbamo­yl]pentan­amido}pyridinium hexa­fluoro­phosphate
title_fullStr 2-{5-[N-(2-Pyridyl)carbamo­yl]pentan­amido}pyridinium hexa­fluoro­phosphate
title_full_unstemmed 2-{5-[N-(2-Pyridyl)carbamo­yl]pentan­amido}pyridinium hexa­fluoro­phosphate
title_short 2-{5-[N-(2-Pyridyl)carbamo­yl]pentan­amido}pyridinium hexa­fluoro­phosphate
title_sort 2-{5-[n-(2-pyridyl)carbamo­yl]pentan­amido}pyridinium hexa­fluoro­phosphate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977368/
https://www.ncbi.nlm.nih.gov/pubmed/21583527
http://dx.doi.org/10.1107/S1600536809026488
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