Bis[1,3-bis­(benzimidazol-2-yl)-2-oxa­propane]cobalt(II) dipicrate acetonitrile tris­olvate

In the title compound, [Co(C(16)H(14)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·3CH(3)CN, the Co(II) ion is located on a crystallographic twofold rotation axis and is coordinated in a slightly distorted tetra­hedral environment by four N atoms from the two bidentate N-heterocycles. The crystal structure is sta...

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Detalles Bibliográficos
Autores principales: Wu, Huilu, Yun, Ruirui, Huang, Xingcai, Sun, Qingyu, Qi, Baoliang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977374/
https://www.ncbi.nlm.nih.gov/pubmed/21583320
http://dx.doi.org/10.1107/S1600536809024234
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author Wu, Huilu
Yun, Ruirui
Huang, Xingcai
Sun, Qingyu
Qi, Baoliang
author_facet Wu, Huilu
Yun, Ruirui
Huang, Xingcai
Sun, Qingyu
Qi, Baoliang
author_sort Wu, Huilu
collection PubMed
description In the title compound, [Co(C(16)H(14)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·3CH(3)CN, the Co(II) ion is located on a crystallographic twofold rotation axis and is coordinated in a slightly distorted tetra­hedral environment by four N atoms from the two bidentate N-heterocycles. The crystal structure is stabilized by inter­molecular N—H⋯O and N—H⋯N hydrogen bonds. One of the acetonitrile solvent mol­ecules also lies on a twofold rotation axis.
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spelling pubmed-29773742010-12-30 Bis[1,3-bis­(benzimidazol-2-yl)-2-oxa­propane]cobalt(II) dipicrate acetonitrile tris­olvate Wu, Huilu Yun, Ruirui Huang, Xingcai Sun, Qingyu Qi, Baoliang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(16)H(14)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·3CH(3)CN, the Co(II) ion is located on a crystallographic twofold rotation axis and is coordinated in a slightly distorted tetra­hedral environment by four N atoms from the two bidentate N-heterocycles. The crystal structure is stabilized by inter­molecular N—H⋯O and N—H⋯N hydrogen bonds. One of the acetonitrile solvent mol­ecules also lies on a twofold rotation axis. International Union of Crystallography 2009-07-01 /pmc/articles/PMC2977374/ /pubmed/21583320 http://dx.doi.org/10.1107/S1600536809024234 Text en © Wu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Huilu
Yun, Ruirui
Huang, Xingcai
Sun, Qingyu
Qi, Baoliang
Bis[1,3-bis­(benzimidazol-2-yl)-2-oxa­propane]cobalt(II) dipicrate acetonitrile tris­olvate
title Bis[1,3-bis­(benzimidazol-2-yl)-2-oxa­propane]cobalt(II) dipicrate acetonitrile tris­olvate
title_full Bis[1,3-bis­(benzimidazol-2-yl)-2-oxa­propane]cobalt(II) dipicrate acetonitrile tris­olvate
title_fullStr Bis[1,3-bis­(benzimidazol-2-yl)-2-oxa­propane]cobalt(II) dipicrate acetonitrile tris­olvate
title_full_unstemmed Bis[1,3-bis­(benzimidazol-2-yl)-2-oxa­propane]cobalt(II) dipicrate acetonitrile tris­olvate
title_short Bis[1,3-bis­(benzimidazol-2-yl)-2-oxa­propane]cobalt(II) dipicrate acetonitrile tris­olvate
title_sort bis[1,3-bis­(benzimidazol-2-yl)-2-oxa­propane]cobalt(ii) dipicrate acetonitrile tris­olvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977374/
https://www.ncbi.nlm.nih.gov/pubmed/21583320
http://dx.doi.org/10.1107/S1600536809024234
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