1,4-Bis(4-pyridylmeth­yl)piperazin-1-ium perchlorate fumaric acid hemisolvate

In the title salt, C(16)H(21)N(4) (+)·ClO(4) (−)·0.5C(4)H(4)O(4), fumaric acid mol­ecules, situated across crystallographic inversion centres, are O—H⋯N hydrogen bonded to two protonated 1,4-bis­(4-pyridylmeth­yl)piperazine cations, forming trimolecular units. These construct one-dimensional supra­m...

Descripción completa

Detalles Bibliográficos
Autores principales: Farnum, Gregory A., LaDuca, Robert L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977376/
https://www.ncbi.nlm.nih.gov/pubmed/21583520
http://dx.doi.org/10.1107/S1600536809026026
_version_ 1782191093506375680
author Farnum, Gregory A.
LaDuca, Robert L.
author_facet Farnum, Gregory A.
LaDuca, Robert L.
author_sort Farnum, Gregory A.
collection PubMed
description In the title salt, C(16)H(21)N(4) (+)·ClO(4) (−)·0.5C(4)H(4)O(4), fumaric acid mol­ecules, situated across crystallographic inversion centres, are O—H⋯N hydrogen bonded to two protonated 1,4-bis­(4-pyridylmeth­yl)piperazine cations, forming trimolecular units. These construct one-dimensional supra­molecular ribbons by N—H⋯N hydrogen bonding, and further aggregate via π–π inter­actions [shortest C⋯C contact = 3.640 (1) Å] and perchlorate-mediated C—H⋯O inter­actions.
format Text
id pubmed-2977376
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29773762010-12-30 1,4-Bis(4-pyridylmeth­yl)piperazin-1-ium perchlorate fumaric acid hemisolvate Farnum, Gregory A. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(16)H(21)N(4) (+)·ClO(4) (−)·0.5C(4)H(4)O(4), fumaric acid mol­ecules, situated across crystallographic inversion centres, are O—H⋯N hydrogen bonded to two protonated 1,4-bis­(4-pyridylmeth­yl)piperazine cations, forming trimolecular units. These construct one-dimensional supra­molecular ribbons by N—H⋯N hydrogen bonding, and further aggregate via π–π inter­actions [shortest C⋯C contact = 3.640 (1) Å] and perchlorate-mediated C—H⋯O inter­actions. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977376/ /pubmed/21583520 http://dx.doi.org/10.1107/S1600536809026026 Text en © Farnum and LaDuca 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Farnum, Gregory A.
LaDuca, Robert L.
1,4-Bis(4-pyridylmeth­yl)piperazin-1-ium perchlorate fumaric acid hemisolvate
title 1,4-Bis(4-pyridylmeth­yl)piperazin-1-ium perchlorate fumaric acid hemisolvate
title_full 1,4-Bis(4-pyridylmeth­yl)piperazin-1-ium perchlorate fumaric acid hemisolvate
title_fullStr 1,4-Bis(4-pyridylmeth­yl)piperazin-1-ium perchlorate fumaric acid hemisolvate
title_full_unstemmed 1,4-Bis(4-pyridylmeth­yl)piperazin-1-ium perchlorate fumaric acid hemisolvate
title_short 1,4-Bis(4-pyridylmeth­yl)piperazin-1-ium perchlorate fumaric acid hemisolvate
title_sort 1,4-bis(4-pyridylmeth­yl)piperazin-1-ium perchlorate fumaric acid hemisolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977376/
https://www.ncbi.nlm.nih.gov/pubmed/21583520
http://dx.doi.org/10.1107/S1600536809026026
work_keys_str_mv AT farnumgregorya 14bis4pyridylmethylpiperazin1iumperchloratefumaricacidhemisolvate
AT laducarobertl 14bis4pyridylmethylpiperazin1iumperchloratefumaricacidhemisolvate

Ejemplares similares