{Bis[2-(diphenyl­phosphino)phen­yl] ether-κ(2) P:P′}(dimethyl 2,2′-biphenyl-4,4′-dicarboxyl­ate-κ(2) N:N′)copper(I) hexa­fluorido­phosphate acetonitrile solvate

In the title compound, [Cu(C(14)H(12)N(2)O(4))(C(36)H(28)OP(2))]PF(6)·CH(3)CN, the Cu(I) ion is coordinated by two N atoms from the dimethyl 2,2′-biphenyl-4,4′-dicarboxyl­ate ligand and two P atoms from the bis­[2-(diphenyl­phosphino)phen­yl] ether ligand in a distorted tetra­hedral environment. In...

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Detalles Bibliográficos
Autores principales: Yu, Ai-Guo, Zhang, Ming, Yang, Guang-Di, Ye, Ling, Ma, Yu-Guang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977378/
https://www.ncbi.nlm.nih.gov/pubmed/21583340
http://dx.doi.org/10.1107/S1600536809024982
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author Yu, Ai-Guo
Zhang, Ming
Yang, Guang-Di
Ye, Ling
Ma, Yu-Guang
author_facet Yu, Ai-Guo
Zhang, Ming
Yang, Guang-Di
Ye, Ling
Ma, Yu-Guang
author_sort Yu, Ai-Guo
collection PubMed
description In the title compound, [Cu(C(14)H(12)N(2)O(4))(C(36)H(28)OP(2))]PF(6)·CH(3)CN, the Cu(I) ion is coordinated by two N atoms from the dimethyl 2,2′-biphenyl-4,4′-dicarboxyl­ate ligand and two P atoms from the bis­[2-(diphenyl­phosphino)phen­yl] ether ligand in a distorted tetra­hedral environment. In the cation, the short distance of 3.870 (4) Å between the centroids of the benzene and phenyl rings suggests the existence of intra­molecular π–π inter­actions.
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spelling pubmed-29773782010-12-30 {Bis[2-(diphenyl­phosphino)phen­yl] ether-κ(2) P:P′}(dimethyl 2,2′-biphenyl-4,4′-dicarboxyl­ate-κ(2) N:N′)copper(I) hexa­fluorido­phosphate acetonitrile solvate Yu, Ai-Guo Zhang, Ming Yang, Guang-Di Ye, Ling Ma, Yu-Guang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(14)H(12)N(2)O(4))(C(36)H(28)OP(2))]PF(6)·CH(3)CN, the Cu(I) ion is coordinated by two N atoms from the dimethyl 2,2′-biphenyl-4,4′-dicarboxyl­ate ligand and two P atoms from the bis­[2-(diphenyl­phosphino)phen­yl] ether ligand in a distorted tetra­hedral environment. In the cation, the short distance of 3.870 (4) Å between the centroids of the benzene and phenyl rings suggests the existence of intra­molecular π–π inter­actions. International Union of Crystallography 2009-07-04 /pmc/articles/PMC2977378/ /pubmed/21583340 http://dx.doi.org/10.1107/S1600536809024982 Text en © Yu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Ai-Guo
Zhang, Ming
Yang, Guang-Di
Ye, Ling
Ma, Yu-Guang
{Bis[2-(diphenyl­phosphino)phen­yl] ether-κ(2) P:P′}(dimethyl 2,2′-biphenyl-4,4′-dicarboxyl­ate-κ(2) N:N′)copper(I) hexa­fluorido­phosphate acetonitrile solvate
title {Bis[2-(diphenyl­phosphino)phen­yl] ether-κ(2) P:P′}(dimethyl 2,2′-biphenyl-4,4′-dicarboxyl­ate-κ(2) N:N′)copper(I) hexa­fluorido­phosphate acetonitrile solvate
title_full {Bis[2-(diphenyl­phosphino)phen­yl] ether-κ(2) P:P′}(dimethyl 2,2′-biphenyl-4,4′-dicarboxyl­ate-κ(2) N:N′)copper(I) hexa­fluorido­phosphate acetonitrile solvate
title_fullStr {Bis[2-(diphenyl­phosphino)phen­yl] ether-κ(2) P:P′}(dimethyl 2,2′-biphenyl-4,4′-dicarboxyl­ate-κ(2) N:N′)copper(I) hexa­fluorido­phosphate acetonitrile solvate
title_full_unstemmed {Bis[2-(diphenyl­phosphino)phen­yl] ether-κ(2) P:P′}(dimethyl 2,2′-biphenyl-4,4′-dicarboxyl­ate-κ(2) N:N′)copper(I) hexa­fluorido­phosphate acetonitrile solvate
title_short {Bis[2-(diphenyl­phosphino)phen­yl] ether-κ(2) P:P′}(dimethyl 2,2′-biphenyl-4,4′-dicarboxyl­ate-κ(2) N:N′)copper(I) hexa­fluorido­phosphate acetonitrile solvate
title_sort {bis[2-(diphenyl­phosphino)phen­yl] ether-κ(2) p:p′}(dimethyl 2,2′-biphenyl-4,4′-dicarboxyl­ate-κ(2) n:n′)copper(i) hexa­fluorido­phosphate acetonitrile solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977378/
https://www.ncbi.nlm.nih.gov/pubmed/21583340
http://dx.doi.org/10.1107/S1600536809024982
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AT zhangming bis2diphenylphosphinophenyletherk2ppdimethyl22biphenyl44dicarboxylatek2nncopperihexafluoridophosphateacetonitrilesolvate
AT yangguangdi bis2diphenylphosphinophenyletherk2ppdimethyl22biphenyl44dicarboxylatek2nncopperihexafluoridophosphateacetonitrilesolvate
AT yeling bis2diphenylphosphinophenyletherk2ppdimethyl22biphenyl44dicarboxylatek2nncopperihexafluoridophosphateacetonitrilesolvate
AT mayuguang bis2diphenylphosphinophenyletherk2ppdimethyl22biphenyl44dicarboxylatek2nncopperihexafluoridophosphateacetonitrilesolvate

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