1,1′,2,2′-Tetra­methyl-3,3′-(p-phenyl­enedimethyl­ene)diimidazol-1-ium dibromide

The title imidazolium-based ionic-liquid salt, C(18)H(24)N(4) (2+)·2Br(−), has the cation lying about a center of inversion. The five-membered imidazole ring is disordered over two positions with the major component having a site occupancy of 0.712 (4); the N-bound methyl substituents are ordered. T...

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Detalles Bibliográficos
Autores principales: Puvaneswary, Subramaniam, Alias, Yatimah, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977381/
https://www.ncbi.nlm.nih.gov/pubmed/21583530
http://dx.doi.org/10.1107/S1600536809026324
Descripción
Sumario:The title imidazolium-based ionic-liquid salt, C(18)H(24)N(4) (2+)·2Br(−), has the cation lying about a center of inversion. The five-membered imidazole ring is disordered over two positions with the major component having a site occupancy of 0.712 (4); the N-bound methyl substituents are ordered. The imidazole ring is approximately perpendicular to the six-membered phenyl­ene ring [dihedral angle = 80.7 (5)° for the major disorder component and 89.8 (3)° for the other; the two components are off-set by 10.1 (6)°].

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