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(Z)-1-(2,5-Dichloro-3-thien­yl)ethanone semicarbazone

The title mol­ecule, C(7)H(7)Cl(2)N(3)OS, is approximately planar [maximum deviation = 0.062 (1) Å]. Short inter­molecular distances between the centroids of the five-membered rings [3.5340 (8) Å] indicate the existence of π–π inter­actions. An inter­esting feature of the crystal structure is the pr...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Quah, Ching Kheng, Vijesh, A. M., Hegde, Chitrakar, Isloor, Arun M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977384/
https://www.ncbi.nlm.nih.gov/pubmed/21583552
http://dx.doi.org/10.1107/S1600536809026567
Descripción
Sumario:The title mol­ecule, C(7)H(7)Cl(2)N(3)OS, is approximately planar [maximum deviation = 0.062 (1) Å]. Short inter­molecular distances between the centroids of the five-membered rings [3.5340 (8) Å] indicate the existence of π–π inter­actions. An inter­esting feature of the crystal structure is the presence of short intra­molecular Cl⋯N inter­actions [3.0015 (11) Å]. Mol­ecules are linked via pairs of inter­molecular N—H⋯O hydrogen bonds, generating R (2) (2)(8) ring motifs. Furthermore, N—H⋯O hydrogen bonds form R (2) (1)(7) ring motifs with C—H⋯O contacts, further consolidating the crystal structure. In the crystal, mol­ecules are linked by these inter­molecular inter­actions, forming chains along [001].