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(Z)-1-(2,5-Dichloro-3-thienyl)ethanone semicarbazone
The title molecule, C(7)H(7)Cl(2)N(3)OS, is approximately planar [maximum deviation = 0.062 (1) Å]. Short intermolecular distances between the centroids of the five-membered rings [3.5340 (8) Å] indicate the existence of π–π interactions. An interesting feature of the crystal structure is the pr...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977384/ https://www.ncbi.nlm.nih.gov/pubmed/21583552 http://dx.doi.org/10.1107/S1600536809026567 |
Sumario: | The title molecule, C(7)H(7)Cl(2)N(3)OS, is approximately planar [maximum deviation = 0.062 (1) Å]. Short intermolecular distances between the centroids of the five-membered rings [3.5340 (8) Å] indicate the existence of π–π interactions. An interesting feature of the crystal structure is the presence of short intramolecular Cl⋯N interactions [3.0015 (11) Å]. Molecules are linked via pairs of intermolecular N—H⋯O hydrogen bonds, generating R (2) (2)(8) ring motifs. Furthermore, N—H⋯O hydrogen bonds form R (2) (1)(7) ring motifs with C—H⋯O contacts, further consolidating the crystal structure. In the crystal, molecules are linked by these intermolecular interactions, forming chains along [001]. |
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