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(Z)-1-(2,5-Dichloro-3-thienyl)ethanone semicarbazone
The title molecule, C(7)H(7)Cl(2)N(3)OS, is approximately planar [maximum deviation = 0.062 (1) Å]. Short intermolecular distances between the centroids of the five-membered rings [3.5340 (8) Å] indicate the existence of π–π interactions. An interesting feature of the crystal structure is the pr...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977384/ https://www.ncbi.nlm.nih.gov/pubmed/21583552 http://dx.doi.org/10.1107/S1600536809026567 |
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author | Fun, Hoong-Kun Quah, Ching Kheng Vijesh, A. M. Hegde, Chitrakar Isloor, Arun M. |
author_facet | Fun, Hoong-Kun Quah, Ching Kheng Vijesh, A. M. Hegde, Chitrakar Isloor, Arun M. |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | The title molecule, C(7)H(7)Cl(2)N(3)OS, is approximately planar [maximum deviation = 0.062 (1) Å]. Short intermolecular distances between the centroids of the five-membered rings [3.5340 (8) Å] indicate the existence of π–π interactions. An interesting feature of the crystal structure is the presence of short intramolecular Cl⋯N interactions [3.0015 (11) Å]. Molecules are linked via pairs of intermolecular N—H⋯O hydrogen bonds, generating R (2) (2)(8) ring motifs. Furthermore, N—H⋯O hydrogen bonds form R (2) (1)(7) ring motifs with C—H⋯O contacts, further consolidating the crystal structure. In the crystal, molecules are linked by these intermolecular interactions, forming chains along [001]. |
format | Text |
id | pubmed-2977384 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29773842010-12-30 (Z)-1-(2,5-Dichloro-3-thienyl)ethanone semicarbazone Fun, Hoong-Kun Quah, Ching Kheng Vijesh, A. M. Hegde, Chitrakar Isloor, Arun M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title molecule, C(7)H(7)Cl(2)N(3)OS, is approximately planar [maximum deviation = 0.062 (1) Å]. Short intermolecular distances between the centroids of the five-membered rings [3.5340 (8) Å] indicate the existence of π–π interactions. An interesting feature of the crystal structure is the presence of short intramolecular Cl⋯N interactions [3.0015 (11) Å]. Molecules are linked via pairs of intermolecular N—H⋯O hydrogen bonds, generating R (2) (2)(8) ring motifs. Furthermore, N—H⋯O hydrogen bonds form R (2) (1)(7) ring motifs with C—H⋯O contacts, further consolidating the crystal structure. In the crystal, molecules are linked by these intermolecular interactions, forming chains along [001]. International Union of Crystallography 2009-07-15 /pmc/articles/PMC2977384/ /pubmed/21583552 http://dx.doi.org/10.1107/S1600536809026567 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Quah, Ching Kheng Vijesh, A. M. Hegde, Chitrakar Isloor, Arun M. (Z)-1-(2,5-Dichloro-3-thienyl)ethanone semicarbazone |
title | (Z)-1-(2,5-Dichloro-3-thienyl)ethanone semicarbazone |
title_full | (Z)-1-(2,5-Dichloro-3-thienyl)ethanone semicarbazone |
title_fullStr | (Z)-1-(2,5-Dichloro-3-thienyl)ethanone semicarbazone |
title_full_unstemmed | (Z)-1-(2,5-Dichloro-3-thienyl)ethanone semicarbazone |
title_short | (Z)-1-(2,5-Dichloro-3-thienyl)ethanone semicarbazone |
title_sort | (z)-1-(2,5-dichloro-3-thienyl)ethanone semicarbazone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977384/ https://www.ncbi.nlm.nih.gov/pubmed/21583552 http://dx.doi.org/10.1107/S1600536809026567 |
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