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{2,2′-[o-Phenylenebis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate
The title compound, [Co(C(20)H(14)N(2)O(2))(C(5)H(5)N)(2)]ClO(4) or [Co(salophen)(py)(2)]ClO(4), where salophen is o-phenylenebis(nitrilomethylidyne)]diphenolate and py is pyridine, contains a six-coordinate mononuclear cobalt(III) atom. The two phenolic O atoms and the two imine N atoms are loca...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977385/ https://www.ncbi.nlm.nih.gov/pubmed/21583393 http://dx.doi.org/10.1107/S1600536809027330 |
Sumario: | The title compound, [Co(C(20)H(14)N(2)O(2))(C(5)H(5)N)(2)]ClO(4) or [Co(salophen)(py)(2)]ClO(4), where salophen is o-phenylenebis(nitrilomethylidyne)]diphenolate and py is pyridine, contains a six-coordinate mononuclear cobalt(III) atom. The two phenolic O atoms and the two imine N atoms are located in cis positions. There are two pyridine molecules attached to the metal atom, filling the axial sites with a mutually perpendicular disposition of the pyridine planes [86.11 (5)°]. The Co complexes are stacked in layers parallel to (100). Coherence of the structure is provided by a variety of C—H⋯O interactions between the complexes and the perchlorate counter anion. |
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