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{2,2′-[o-Phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}dipyridinecobalt(III) perchlorate

The title compound, [Co(C(20)H(14)N(2)O(2))(C(5)H(5)N)(2)]ClO(4) or [Co(salophen)(py)(2)]ClO(4), where salophen is o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolate and py is pyridine, contains a six-coordinate mononuclear cobalt(III) atom. The two phenolic O atoms and the two imine N atoms are loca...

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Detalles Bibliográficos
Autores principales: Salehi, Mehdi, Meghdadi, Soraia, Amirnasr, Mehdi, Mereiter, Kurt
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977385/
https://www.ncbi.nlm.nih.gov/pubmed/21583393
http://dx.doi.org/10.1107/S1600536809027330
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author Salehi, Mehdi
Meghdadi, Soraia
Amirnasr, Mehdi
Mereiter, Kurt
author_facet Salehi, Mehdi
Meghdadi, Soraia
Amirnasr, Mehdi
Mereiter, Kurt
author_sort Salehi, Mehdi
collection PubMed
description The title compound, [Co(C(20)H(14)N(2)O(2))(C(5)H(5)N)(2)]ClO(4) or [Co(salophen)(py)(2)]ClO(4), where salophen is o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolate and py is pyridine, contains a six-coordinate mononuclear cobalt(III) atom. The two phenolic O atoms and the two imine N atoms are located in cis positions. There are two pyridine mol­ecules attached to the metal atom, filling the axial sites with a mutually perpendicular disposition of the pyridine planes [86.11 (5)°]. The Co complexes are stacked in layers parallel to (100). Coherence of the structure is provided by a variety of C—H⋯O interactions between the complexes and the perchlor­ate counter anion.
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spelling pubmed-29773852010-12-30 {2,2′-[o-Phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}dipyridinecobalt(III) perchlorate Salehi, Mehdi Meghdadi, Soraia Amirnasr, Mehdi Mereiter, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(20)H(14)N(2)O(2))(C(5)H(5)N)(2)]ClO(4) or [Co(salophen)(py)(2)]ClO(4), where salophen is o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolate and py is pyridine, contains a six-coordinate mononuclear cobalt(III) atom. The two phenolic O atoms and the two imine N atoms are located in cis positions. There are two pyridine mol­ecules attached to the metal atom, filling the axial sites with a mutually perpendicular disposition of the pyridine planes [86.11 (5)°]. The Co complexes are stacked in layers parallel to (100). Coherence of the structure is provided by a variety of C—H⋯O interactions between the complexes and the perchlor­ate counter anion. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977385/ /pubmed/21583393 http://dx.doi.org/10.1107/S1600536809027330 Text en © Salehi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Salehi, Mehdi
Meghdadi, Soraia
Amirnasr, Mehdi
Mereiter, Kurt
{2,2′-[o-Phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}dipyridinecobalt(III) perchlorate
title {2,2′-[o-Phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}dipyridinecobalt(III) perchlorate
title_full {2,2′-[o-Phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}dipyridinecobalt(III) perchlorate
title_fullStr {2,2′-[o-Phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}dipyridinecobalt(III) perchlorate
title_full_unstemmed {2,2′-[o-Phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}dipyridinecobalt(III) perchlorate
title_short {2,2′-[o-Phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}dipyridinecobalt(III) perchlorate
title_sort {2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}dipyridinecobalt(iii) perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977385/
https://www.ncbi.nlm.nih.gov/pubmed/21583393
http://dx.doi.org/10.1107/S1600536809027330
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