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{2,2′-[o-Phenylenebis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate
The title compound, [Co(C(20)H(14)N(2)O(2))(C(5)H(5)N)(2)]ClO(4) or [Co(salophen)(py)(2)]ClO(4), where salophen is o-phenylenebis(nitrilomethylidyne)]diphenolate and py is pyridine, contains a six-coordinate mononuclear cobalt(III) atom. The two phenolic O atoms and the two imine N atoms are loca...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977385/ https://www.ncbi.nlm.nih.gov/pubmed/21583393 http://dx.doi.org/10.1107/S1600536809027330 |
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author | Salehi, Mehdi Meghdadi, Soraia Amirnasr, Mehdi Mereiter, Kurt |
author_facet | Salehi, Mehdi Meghdadi, Soraia Amirnasr, Mehdi Mereiter, Kurt |
author_sort | Salehi, Mehdi |
collection | PubMed |
description | The title compound, [Co(C(20)H(14)N(2)O(2))(C(5)H(5)N)(2)]ClO(4) or [Co(salophen)(py)(2)]ClO(4), where salophen is o-phenylenebis(nitrilomethylidyne)]diphenolate and py is pyridine, contains a six-coordinate mononuclear cobalt(III) atom. The two phenolic O atoms and the two imine N atoms are located in cis positions. There are two pyridine molecules attached to the metal atom, filling the axial sites with a mutually perpendicular disposition of the pyridine planes [86.11 (5)°]. The Co complexes are stacked in layers parallel to (100). Coherence of the structure is provided by a variety of C—H⋯O interactions between the complexes and the perchlorate counter anion. |
format | Text |
id | pubmed-2977385 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29773852010-12-30 {2,2′-[o-Phenylenebis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate Salehi, Mehdi Meghdadi, Soraia Amirnasr, Mehdi Mereiter, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(20)H(14)N(2)O(2))(C(5)H(5)N)(2)]ClO(4) or [Co(salophen)(py)(2)]ClO(4), where salophen is o-phenylenebis(nitrilomethylidyne)]diphenolate and py is pyridine, contains a six-coordinate mononuclear cobalt(III) atom. The two phenolic O atoms and the two imine N atoms are located in cis positions. There are two pyridine molecules attached to the metal atom, filling the axial sites with a mutually perpendicular disposition of the pyridine planes [86.11 (5)°]. The Co complexes are stacked in layers parallel to (100). Coherence of the structure is provided by a variety of C—H⋯O interactions between the complexes and the perchlorate counter anion. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977385/ /pubmed/21583393 http://dx.doi.org/10.1107/S1600536809027330 Text en © Salehi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Salehi, Mehdi Meghdadi, Soraia Amirnasr, Mehdi Mereiter, Kurt {2,2′-[o-Phenylenebis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate |
title | {2,2′-[o-Phenylenebis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate |
title_full | {2,2′-[o-Phenylenebis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate |
title_fullStr | {2,2′-[o-Phenylenebis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate |
title_full_unstemmed | {2,2′-[o-Phenylenebis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate |
title_short | {2,2′-[o-Phenylenebis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate |
title_sort | {2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(iii) perchlorate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977385/ https://www.ncbi.nlm.nih.gov/pubmed/21583393 http://dx.doi.org/10.1107/S1600536809027330 |
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