2,5-Dioxopyrrolidin-1-yl adamantane-1-carboxyl­ate

The title compound, C(15)H(19)NO(4), contains one crystallographically independent mol­ecule in the asymmetric unit. The N—O—C—O torsion angle is 1.97 (9)°. The two pairs of vicinal H atoms that lie above or below the plane defined by the five-membered pyrrolidine-2,5-dione ring are an average of 6....

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Detalles Bibliográficos
Autores principales: Liu, Joe, Clegg, Jack K., Codd, Rachel
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977389/
https://www.ncbi.nlm.nih.gov/pubmed/21583453
http://dx.doi.org/10.1107/S1600536809024209
Descripción
Sumario:The title compound, C(15)H(19)NO(4), contains one crystallographically independent mol­ecule in the asymmetric unit. The N—O—C—O torsion angle is 1.97 (9)°. The two pairs of vicinal H atoms that lie above or below the plane defined by the five-membered pyrrolidine-2,5-dione ring are an average of 6.57 (5)° from being eclipsed. The average absolute C—C—C—C torsion angle in the adamantane skeleton, in which each fused cyclo­hexane ring is in a chair configuration, is 59.99 (5)°. The crystal packing is unremarkable.

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