2,5-Dioxopyrrolidin-1-yl adamantane-1-carboxyl­ate

The title compound, C(15)H(19)NO(4), contains one crystallographically independent mol­ecule in the asymmetric unit. The N—O—C—O torsion angle is 1.97 (9)°. The two pairs of vicinal H atoms that lie above or below the plane defined by the five-membered pyrrolidine-2,5-dione ring are an average of 6....

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Detalles Bibliográficos
Autores principales: Liu, Joe, Clegg, Jack K., Codd, Rachel
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977389/
https://www.ncbi.nlm.nih.gov/pubmed/21583453
http://dx.doi.org/10.1107/S1600536809024209
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author Liu, Joe
Clegg, Jack K.
Codd, Rachel
author_facet Liu, Joe
Clegg, Jack K.
Codd, Rachel
author_sort Liu, Joe
collection PubMed
description The title compound, C(15)H(19)NO(4), contains one crystallographically independent mol­ecule in the asymmetric unit. The N—O—C—O torsion angle is 1.97 (9)°. The two pairs of vicinal H atoms that lie above or below the plane defined by the five-membered pyrrolidine-2,5-dione ring are an average of 6.57 (5)° from being eclipsed. The average absolute C—C—C—C torsion angle in the adamantane skeleton, in which each fused cyclo­hexane ring is in a chair configuration, is 59.99 (5)°. The crystal packing is unremarkable.
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spelling pubmed-29773892010-12-30 2,5-Dioxopyrrolidin-1-yl adamantane-1-carboxyl­ate Liu, Joe Clegg, Jack K. Codd, Rachel Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(19)NO(4), contains one crystallographically independent mol­ecule in the asymmetric unit. The N—O—C—O torsion angle is 1.97 (9)°. The two pairs of vicinal H atoms that lie above or below the plane defined by the five-membered pyrrolidine-2,5-dione ring are an average of 6.57 (5)° from being eclipsed. The average absolute C—C—C—C torsion angle in the adamantane skeleton, in which each fused cyclo­hexane ring is in a chair configuration, is 59.99 (5)°. The crystal packing is unremarkable. International Union of Crystallography 2009-07-04 /pmc/articles/PMC2977389/ /pubmed/21583453 http://dx.doi.org/10.1107/S1600536809024209 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Joe
Clegg, Jack K.
Codd, Rachel
2,5-Dioxopyrrolidin-1-yl adamantane-1-carboxyl­ate
title 2,5-Dioxopyrrolidin-1-yl adamantane-1-carboxyl­ate
title_full 2,5-Dioxopyrrolidin-1-yl adamantane-1-carboxyl­ate
title_fullStr 2,5-Dioxopyrrolidin-1-yl adamantane-1-carboxyl­ate
title_full_unstemmed 2,5-Dioxopyrrolidin-1-yl adamantane-1-carboxyl­ate
title_short 2,5-Dioxopyrrolidin-1-yl adamantane-1-carboxyl­ate
title_sort 2,5-dioxopyrrolidin-1-yl adamantane-1-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977389/
https://www.ncbi.nlm.nih.gov/pubmed/21583453
http://dx.doi.org/10.1107/S1600536809024209
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AT cleggjackk 25dioxopyrrolidin1yladamantane1carboxylate
AT coddrachel 25dioxopyrrolidin1yladamantane1carboxylate

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