N-(4-Hydr­oxy-3-methoxy­benz­yl)benzamide

In the mol­ecular structure of the title compound, C(15)H(15)NO(3), the two benzene rings are twisted with respect to each other, making a dihedral angle of 75.11 (10)°. In the amide fragment, the C=O and C—N bond distances are 1.248 (3) and 1.321 (3) Å, respectively, indicating electron delocalizat...

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Detalles Bibliográficos
Autores principales: Xia, Liang-You, Wang, Wen-Long, Wang, Shan-Heng, Huang, Yan-Lan, Shan, Shang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977390/
https://www.ncbi.nlm.nih.gov/pubmed/21583589
http://dx.doi.org/10.1107/S1600536809027500
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author Xia, Liang-You
Wang, Wen-Long
Wang, Shan-Heng
Huang, Yan-Lan
Shan, Shang
author_facet Xia, Liang-You
Wang, Wen-Long
Wang, Shan-Heng
Huang, Yan-Lan
Shan, Shang
author_sort Xia, Liang-You
collection PubMed
description In the mol­ecular structure of the title compound, C(15)H(15)NO(3), the two benzene rings are twisted with respect to each other, making a dihedral angle of 75.11 (10)°. In the amide fragment, the C=O and C—N bond distances are 1.248 (3) and 1.321 (3) Å, respectively, indicating electron delocalization. A partially ovelapped arrangement between parallel hydroxy­methoxy­benzene rings is observed in the crystal structure, and the face-to-face distance of 3.531 (16) Å suggests the existence of weak π–π stacking. N—H⋯O and O—H⋯O hydrogen bonding is also present in the crystal structure.
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spelling pubmed-29773902010-12-30 N-(4-Hydr­oxy-3-methoxy­benz­yl)benzamide Xia, Liang-You Wang, Wen-Long Wang, Shan-Heng Huang, Yan-Lan Shan, Shang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecular structure of the title compound, C(15)H(15)NO(3), the two benzene rings are twisted with respect to each other, making a dihedral angle of 75.11 (10)°. In the amide fragment, the C=O and C—N bond distances are 1.248 (3) and 1.321 (3) Å, respectively, indicating electron delocalization. A partially ovelapped arrangement between parallel hydroxy­methoxy­benzene rings is observed in the crystal structure, and the face-to-face distance of 3.531 (16) Å suggests the existence of weak π–π stacking. N—H⋯O and O—H⋯O hydrogen bonding is also present in the crystal structure. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977390/ /pubmed/21583589 http://dx.doi.org/10.1107/S1600536809027500 Text en © Xia et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xia, Liang-You
Wang, Wen-Long
Wang, Shan-Heng
Huang, Yan-Lan
Shan, Shang
N-(4-Hydr­oxy-3-methoxy­benz­yl)benzamide
title N-(4-Hydr­oxy-3-methoxy­benz­yl)benzamide
title_full N-(4-Hydr­oxy-3-methoxy­benz­yl)benzamide
title_fullStr N-(4-Hydr­oxy-3-methoxy­benz­yl)benzamide
title_full_unstemmed N-(4-Hydr­oxy-3-methoxy­benz­yl)benzamide
title_short N-(4-Hydr­oxy-3-methoxy­benz­yl)benzamide
title_sort n-(4-hydr­oxy-3-methoxy­benz­yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977390/
https://www.ncbi.nlm.nih.gov/pubmed/21583589
http://dx.doi.org/10.1107/S1600536809027500
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AT wangwenlong n4hydroxy3methoxybenzylbenzamide
AT wangshanheng n4hydroxy3methoxybenzylbenzamide
AT huangyanlan n4hydroxy3methoxybenzylbenzamide
AT shanshang n4hydroxy3methoxybenzylbenzamide

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