Di-μ-benzoato-κ(3) O,O′:O;κ(3) O:O,O′-bis­[(acetato-κO)(1,10-phenanthroline-κ(2) N,N′)lead(II)] dihydrate

The title compound, [Pb(2)(CH(3)COO)(2)(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(2)]·2H(2)O, consists of dimeric units built up around a crystallographic centre of symmetry and two non-coordinating water mol­ecules. Each Pb(II) unit is six-coordinated by a bidentate 1,10-phenanthroline (phen) ligand, a monod...

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Detalles Bibliográficos
Autores principales: Gao, Junli, Xuan, Xiaopeng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977393/
https://www.ncbi.nlm.nih.gov/pubmed/21583360
http://dx.doi.org/10.1107/S1600536809025896
Descripción
Sumario:The title compound, [Pb(2)(CH(3)COO)(2)(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(2)]·2H(2)O, consists of dimeric units built up around a crystallographic centre of symmetry and two non-coordinating water mol­ecules. Each Pb(II) unit is six-coordinated by a bidentate 1,10-phenanthroline (phen) ligand, a monodentate acetate anion and a bidentate benzoate anion, which also acts as a bridge linking the two Pb(II) atoms. The crystal packing is stabilized by O—H⋯O hydrogen bonds and by π–π inter­actions between the phen rings of neighboring mol­ecules, with a centroid–centroid distance of 3.577 (3) Å.

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