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Di-μ-benzoato-κ(3) O,O′:O;κ(3) O:O,O′-bis[(acetato-κO)(1,10-phenanthroline-κ(2) N,N′)lead(II)] dihydrate
The title compound, [Pb(2)(CH(3)COO)(2)(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(2)]·2H(2)O, consists of dimeric units built up around a crystallographic centre of symmetry and two non-coordinating water molecules. Each Pb(II) unit is six-coordinated by a bidentate 1,10-phenanthroline (phen) ligand, a monod...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977393/ https://www.ncbi.nlm.nih.gov/pubmed/21583360 http://dx.doi.org/10.1107/S1600536809025896 |
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| author | Gao, Junli Xuan, Xiaopeng |
| author_facet | Gao, Junli Xuan, Xiaopeng |
| author_sort | Gao, Junli |
| collection | PubMed |
| description | The title compound, [Pb(2)(CH(3)COO)(2)(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(2)]·2H(2)O, consists of dimeric units built up around a crystallographic centre of symmetry and two non-coordinating water molecules. Each Pb(II) unit is six-coordinated by a bidentate 1,10-phenanthroline (phen) ligand, a monodentate acetate anion and a bidentate benzoate anion, which also acts as a bridge linking the two Pb(II) atoms. The crystal packing is stabilized by O—H⋯O hydrogen bonds and by π–π interactions between the phen rings of neighboring molecules, with a centroid–centroid distance of 3.577 (3) Å. |
| format | Text |
| id | pubmed-2977393 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29773932010-12-30 Di-μ-benzoato-κ(3) O,O′:O;κ(3) O:O,O′-bis[(acetato-κO)(1,10-phenanthroline-κ(2) N,N′)lead(II)] dihydrate Gao, Junli Xuan, Xiaopeng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pb(2)(CH(3)COO)(2)(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(2)]·2H(2)O, consists of dimeric units built up around a crystallographic centre of symmetry and two non-coordinating water molecules. Each Pb(II) unit is six-coordinated by a bidentate 1,10-phenanthroline (phen) ligand, a monodentate acetate anion and a bidentate benzoate anion, which also acts as a bridge linking the two Pb(II) atoms. The crystal packing is stabilized by O—H⋯O hydrogen bonds and by π–π interactions between the phen rings of neighboring molecules, with a centroid–centroid distance of 3.577 (3) Å. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977393/ /pubmed/21583360 http://dx.doi.org/10.1107/S1600536809025896 Text en © Gao and Xuan 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Gao, Junli Xuan, Xiaopeng Di-μ-benzoato-κ(3) O,O′:O;κ(3) O:O,O′-bis[(acetato-κO)(1,10-phenanthroline-κ(2) N,N′)lead(II)] dihydrate |
| title | Di-μ-benzoato-κ(3)
O,O′:O;κ(3)
O:O,O′-bis[(acetato-κO)(1,10-phenanthroline-κ(2)
N,N′)lead(II)] dihydrate |
| title_full | Di-μ-benzoato-κ(3)
O,O′:O;κ(3)
O:O,O′-bis[(acetato-κO)(1,10-phenanthroline-κ(2)
N,N′)lead(II)] dihydrate |
| title_fullStr | Di-μ-benzoato-κ(3)
O,O′:O;κ(3)
O:O,O′-bis[(acetato-κO)(1,10-phenanthroline-κ(2)
N,N′)lead(II)] dihydrate |
| title_full_unstemmed | Di-μ-benzoato-κ(3)
O,O′:O;κ(3)
O:O,O′-bis[(acetato-κO)(1,10-phenanthroline-κ(2)
N,N′)lead(II)] dihydrate |
| title_short | Di-μ-benzoato-κ(3)
O,O′:O;κ(3)
O:O,O′-bis[(acetato-κO)(1,10-phenanthroline-κ(2)
N,N′)lead(II)] dihydrate |
| title_sort | di-μ-benzoato-κ(3)
o,o′:o;κ(3)
o:o,o′-bis[(acetato-κo)(1,10-phenanthroline-κ(2)
n,n′)lead(ii)] dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977393/ https://www.ncbi.nlm.nih.gov/pubmed/21583360 http://dx.doi.org/10.1107/S1600536809025896 |
| work_keys_str_mv | AT gaojunli dimbenzoatok3oook3ooobisacetatoko110phenanthrolinek2nnleadiidihydrate AT xuanxiaopeng dimbenzoatok3oook3ooobisacetatoko110phenanthrolinek2nnleadiidihydrate |