1,4-Diferrocenyl-2-methyl­piperazine-1,4-diium bis­(trifluoro­acetate)

In the title compound, [Fe(2)(C(5)H(5))(2)(C(17)H(24)N(2))](CF(3)COO)(2), the cation possesses a crystallographically imposed inversion centre. The methyl group is disordered over two positions of equal occupancy. The Fe—C bond lengths to the two cyclo­penta­diene rings vary from 2.025 (6) to 2.044 ...

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Detalles Bibliográficos
Autor principal: Chen, Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977395/
https://www.ncbi.nlm.nih.gov/pubmed/21583407
http://dx.doi.org/10.1107/S160053680902426X
Descripción
Sumario:In the title compound, [Fe(2)(C(5)H(5))(2)(C(17)H(24)N(2))](CF(3)COO)(2), the cation possesses a crystallographically imposed inversion centre. The methyl group is disordered over two positions of equal occupancy. The Fe—C bond lengths to the two cyclo­penta­diene rings vary from 2.025 (6) to 2.044 (6) Å. Inter­molecular N—H⋯O and C—H⋯O hydrogen bonds link the cations and anions into a three-dimensional network.

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