1,4-Diferrocenyl-2-methyl­piperazine-1,4-diium bis­(trifluoro­acetate)

In the title compound, [Fe(2)(C(5)H(5))(2)(C(17)H(24)N(2))](CF(3)COO)(2), the cation possesses a crystallographically imposed inversion centre. The methyl group is disordered over two positions of equal occupancy. The Fe—C bond lengths to the two cyclo­penta­diene rings vary from 2.025 (6) to 2.044 ...

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Detalles Bibliográficos
Autor principal: Chen, Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977395/
https://www.ncbi.nlm.nih.gov/pubmed/21583407
http://dx.doi.org/10.1107/S160053680902426X
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author Chen, Fang
author_facet Chen, Fang
author_sort Chen, Fang
collection PubMed
description In the title compound, [Fe(2)(C(5)H(5))(2)(C(17)H(24)N(2))](CF(3)COO)(2), the cation possesses a crystallographically imposed inversion centre. The methyl group is disordered over two positions of equal occupancy. The Fe—C bond lengths to the two cyclo­penta­diene rings vary from 2.025 (6) to 2.044 (6) Å. Inter­molecular N—H⋯O and C—H⋯O hydrogen bonds link the cations and anions into a three-dimensional network.
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spelling pubmed-29773952010-12-30 1,4-Diferrocenyl-2-methyl­piperazine-1,4-diium bis­(trifluoro­acetate) Chen, Fang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(2)(C(5)H(5))(2)(C(17)H(24)N(2))](CF(3)COO)(2), the cation possesses a crystallographically imposed inversion centre. The methyl group is disordered over two positions of equal occupancy. The Fe—C bond lengths to the two cyclo­penta­diene rings vary from 2.025 (6) to 2.044 (6) Å. Inter­molecular N—H⋯O and C—H⋯O hydrogen bonds link the cations and anions into a three-dimensional network. International Union of Crystallography 2009-07-22 /pmc/articles/PMC2977395/ /pubmed/21583407 http://dx.doi.org/10.1107/S160053680902426X Text en © Fang Chen 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Fang
1,4-Diferrocenyl-2-methyl­piperazine-1,4-diium bis­(trifluoro­acetate)
title 1,4-Diferrocenyl-2-methyl­piperazine-1,4-diium bis­(trifluoro­acetate)
title_full 1,4-Diferrocenyl-2-methyl­piperazine-1,4-diium bis­(trifluoro­acetate)
title_fullStr 1,4-Diferrocenyl-2-methyl­piperazine-1,4-diium bis­(trifluoro­acetate)
title_full_unstemmed 1,4-Diferrocenyl-2-methyl­piperazine-1,4-diium bis­(trifluoro­acetate)
title_short 1,4-Diferrocenyl-2-methyl­piperazine-1,4-diium bis­(trifluoro­acetate)
title_sort 1,4-diferrocenyl-2-methyl­piperazine-1,4-diium bis­(trifluoro­acetate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977395/
https://www.ncbi.nlm.nih.gov/pubmed/21583407
http://dx.doi.org/10.1107/S160053680902426X
work_keys_str_mv AT chenfang 14diferrocenyl2methylpiperazine14diiumbistrifluoroacetate

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