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Hexaaquacobalt(II) 5,5′-(propane-1,3-diyldithio)bis(1H-tetrazole-1-acetate)
The asymmetric unit of the title complex, [Co(H(2)O)(6)](C(9)H(10)N(8)O(4)S(2)), contains one-half of a [Co(H(2)O)(6)](2+) cation and one-half of a 5,5′-(propane-1,3-diyldithio)bis(1H-tetrazole-1-acetate) (battp(2−)) anion. The Co(II) center is coordinated by six H(2)O molecules in a distorted oc...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977396/ https://www.ncbi.nlm.nih.gov/pubmed/21583305 http://dx.doi.org/10.1107/S1600536809028463 |
Sumario: | The asymmetric unit of the title complex, [Co(H(2)O)(6)](C(9)H(10)N(8)O(4)S(2)), contains one-half of a [Co(H(2)O)(6)](2+) cation and one-half of a 5,5′-(propane-1,3-diyldithio)bis(1H-tetrazole-1-acetate) (battp(2−)) anion. The Co(II) center is coordinated by six H(2)O molecules in a distorted octahedral coordination environment. In the crystal structure, intra- and intermolecular O—H⋯O and O—H⋯N hydrogen bonds link the cations and anions into a three-dimensional network. π–π contacts between the tetrazole rings [centroid–centroid distance = 3.346 (1) Å] may further stabilize the structure. |
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