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Hexaaquacobalt(II) 5,5′-(propane-1,3-diyldithio)bis(1H-tetrazole-1-acetate)
The asymmetric unit of the title complex, [Co(H(2)O)(6)](C(9)H(10)N(8)O(4)S(2)), contains one-half of a [Co(H(2)O)(6)](2+) cation and one-half of a 5,5′-(propane-1,3-diyldithio)bis(1H-tetrazole-1-acetate) (battp(2−)) anion. The Co(II) center is coordinated by six H(2)O molecules in a distorted oc...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977396/ https://www.ncbi.nlm.nih.gov/pubmed/21583305 http://dx.doi.org/10.1107/S1600536809028463 |
| _version_ | 1782191098252230656 |
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| author | Liang, Wan-Ling Yu, Qing Zhang, Xiu-Qing Qin, Jiang-Ke Liang, Hong |
| author_facet | Liang, Wan-Ling Yu, Qing Zhang, Xiu-Qing Qin, Jiang-Ke Liang, Hong |
| author_sort | Liang, Wan-Ling |
| collection | PubMed |
| description | The asymmetric unit of the title complex, [Co(H(2)O)(6)](C(9)H(10)N(8)O(4)S(2)), contains one-half of a [Co(H(2)O)(6)](2+) cation and one-half of a 5,5′-(propane-1,3-diyldithio)bis(1H-tetrazole-1-acetate) (battp(2−)) anion. The Co(II) center is coordinated by six H(2)O molecules in a distorted octahedral coordination environment. In the crystal structure, intra- and intermolecular O—H⋯O and O—H⋯N hydrogen bonds link the cations and anions into a three-dimensional network. π–π contacts between the tetrazole rings [centroid–centroid distance = 3.346 (1) Å] may further stabilize the structure. |
| format | Text |
| id | pubmed-2977396 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29773962010-12-30 Hexaaquacobalt(II) 5,5′-(propane-1,3-diyldithio)bis(1H-tetrazole-1-acetate) Liang, Wan-Ling Yu, Qing Zhang, Xiu-Qing Qin, Jiang-Ke Liang, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Co(H(2)O)(6)](C(9)H(10)N(8)O(4)S(2)), contains one-half of a [Co(H(2)O)(6)](2+) cation and one-half of a 5,5′-(propane-1,3-diyldithio)bis(1H-tetrazole-1-acetate) (battp(2−)) anion. The Co(II) center is coordinated by six H(2)O molecules in a distorted octahedral coordination environment. In the crystal structure, intra- and intermolecular O—H⋯O and O—H⋯N hydrogen bonds link the cations and anions into a three-dimensional network. π–π contacts between the tetrazole rings [centroid–centroid distance = 3.346 (1) Å] may further stabilize the structure. International Union of Crystallography 2009-07-29 /pmc/articles/PMC2977396/ /pubmed/21583305 http://dx.doi.org/10.1107/S1600536809028463 Text en © Liang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liang, Wan-Ling Yu, Qing Zhang, Xiu-Qing Qin, Jiang-Ke Liang, Hong Hexaaquacobalt(II) 5,5′-(propane-1,3-diyldithio)bis(1H-tetrazole-1-acetate) |
| title | Hexaaquacobalt(II) 5,5′-(propane-1,3-diyldithio)bis(1H-tetrazole-1-acetate) |
| title_full | Hexaaquacobalt(II) 5,5′-(propane-1,3-diyldithio)bis(1H-tetrazole-1-acetate) |
| title_fullStr | Hexaaquacobalt(II) 5,5′-(propane-1,3-diyldithio)bis(1H-tetrazole-1-acetate) |
| title_full_unstemmed | Hexaaquacobalt(II) 5,5′-(propane-1,3-diyldithio)bis(1H-tetrazole-1-acetate) |
| title_short | Hexaaquacobalt(II) 5,5′-(propane-1,3-diyldithio)bis(1H-tetrazole-1-acetate) |
| title_sort | hexaaquacobalt(ii) 5,5′-(propane-1,3-diyldithio)bis(1h-tetrazole-1-acetate) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977396/ https://www.ncbi.nlm.nih.gov/pubmed/21583305 http://dx.doi.org/10.1107/S1600536809028463 |
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