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Chlorido(pentane-2,4-dionato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)

The Cu(II) atom in the title compound, [Cu(C(5)H(7)O(2))Cl(C(12)H(8)N(2))], shows a distorted square-planar coordination; the chelating N and O atoms occupy the basal sites and the Cl atom the apical site. The square-pyramidal character along the Berry D (3h)–C (4v) pseudorotation pathway is 92%.

Detalles Bibliográficos
Autores principales: Wong, Yew Sent, Ng, Chew Hee, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977398/
https://www.ncbi.nlm.nih.gov/pubmed/21583387
http://dx.doi.org/10.1107/S1600536809027111
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author Wong, Yew Sent
Ng, Chew Hee
Ng, Seik Weng
author_facet Wong, Yew Sent
Ng, Chew Hee
Ng, Seik Weng
author_sort Wong, Yew Sent
collection PubMed
description The Cu(II) atom in the title compound, [Cu(C(5)H(7)O(2))Cl(C(12)H(8)N(2))], shows a distorted square-planar coordination; the chelating N and O atoms occupy the basal sites and the Cl atom the apical site. The square-pyramidal character along the Berry D (3h)–C (4v) pseudorotation pathway is 92%.
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spelling pubmed-29773982010-12-30 Chlorido(pentane-2,4-dionato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II) Wong, Yew Sent Ng, Chew Hee Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(II) atom in the title compound, [Cu(C(5)H(7)O(2))Cl(C(12)H(8)N(2))], shows a distorted square-planar coordination; the chelating N and O atoms occupy the basal sites and the Cl atom the apical site. The square-pyramidal character along the Berry D (3h)–C (4v) pseudorotation pathway is 92%. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977398/ /pubmed/21583387 http://dx.doi.org/10.1107/S1600536809027111 Text en © Wong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wong, Yew Sent
Ng, Chew Hee
Ng, Seik Weng
Chlorido(pentane-2,4-dionato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title Chlorido(pentane-2,4-dionato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full Chlorido(pentane-2,4-dionato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_fullStr Chlorido(pentane-2,4-dionato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full_unstemmed Chlorido(pentane-2,4-dionato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_short Chlorido(pentane-2,4-dionato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_sort chlorido(pentane-2,4-dionato-κ(2) o,o′)(1,10-phenanthroline-κ(2) n,n′)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977398/
https://www.ncbi.nlm.nih.gov/pubmed/21583387
http://dx.doi.org/10.1107/S1600536809027111
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