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Chlorido(pentane-2,4-dionato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)
The Cu(II) atom in the title compound, [Cu(C(5)H(7)O(2))Cl(C(12)H(8)N(2))], shows a distorted square-planar coordination; the chelating N and O atoms occupy the basal sites and the Cl atom the apical site. The square-pyramidal character along the Berry D (3h)–C (4v) pseudorotation pathway is 92%.
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977398/ https://www.ncbi.nlm.nih.gov/pubmed/21583387 http://dx.doi.org/10.1107/S1600536809027111 |
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author | Wong, Yew Sent Ng, Chew Hee Ng, Seik Weng |
author_facet | Wong, Yew Sent Ng, Chew Hee Ng, Seik Weng |
author_sort | Wong, Yew Sent |
collection | PubMed |
description | The Cu(II) atom in the title compound, [Cu(C(5)H(7)O(2))Cl(C(12)H(8)N(2))], shows a distorted square-planar coordination; the chelating N and O atoms occupy the basal sites and the Cl atom the apical site. The square-pyramidal character along the Berry D (3h)–C (4v) pseudorotation pathway is 92%. |
format | Text |
id | pubmed-2977398 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29773982010-12-30 Chlorido(pentane-2,4-dionato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II) Wong, Yew Sent Ng, Chew Hee Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(II) atom in the title compound, [Cu(C(5)H(7)O(2))Cl(C(12)H(8)N(2))], shows a distorted square-planar coordination; the chelating N and O atoms occupy the basal sites and the Cl atom the apical site. The square-pyramidal character along the Berry D (3h)–C (4v) pseudorotation pathway is 92%. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977398/ /pubmed/21583387 http://dx.doi.org/10.1107/S1600536809027111 Text en © Wong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wong, Yew Sent Ng, Chew Hee Ng, Seik Weng Chlorido(pentane-2,4-dionato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II) |
title | Chlorido(pentane-2,4-dionato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_full | Chlorido(pentane-2,4-dionato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_fullStr | Chlorido(pentane-2,4-dionato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_full_unstemmed | Chlorido(pentane-2,4-dionato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_short | Chlorido(pentane-2,4-dionato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_sort | chlorido(pentane-2,4-dionato-κ(2)
o,o′)(1,10-phenanthroline-κ(2)
n,n′)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977398/ https://www.ncbi.nlm.nih.gov/pubmed/21583387 http://dx.doi.org/10.1107/S1600536809027111 |
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