1,4-Diazo­niabicyclo­[2.2.2]octane diaqua­dichlorido­(oxalato-κ(2) O,O′)iron(III) chloride

In the title compound, (C(6)H(14)N(2))[Fe(C(2)O(4))Cl(2)(H(2)O)(2)]Cl, all ions are situated on twofold rotational axes. The Fe(III) ion is coordinated by two O atoms from a chelating oxalate ligand, two water mol­ecules and two chloride anions in a distorted octa­hedral geometry. Inter­molecular N—...

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Detalles Bibliográficos
Autor principal: Cai, Ying
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977407/
https://www.ncbi.nlm.nih.gov/pubmed/21583342
http://dx.doi.org/10.1107/S1600536809025628
Descripción
Sumario:In the title compound, (C(6)H(14)N(2))[Fe(C(2)O(4))Cl(2)(H(2)O)(2)]Cl, all ions are situated on twofold rotational axes. The Fe(III) ion is coordinated by two O atoms from a chelating oxalate ligand, two water mol­ecules and two chloride anions in a distorted octa­hedral geometry. Inter­molecular N—H⋯O, O—H⋯O and O—H⋯Cl hydrogen bonds form an extensive three-dimensional network which consolidates the crystal packing.

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