1,4-Diazo­niabicyclo­[2.2.2]octane diaqua­dichlorido­(oxalato-κ(2) O,O′)iron(III) chloride

In the title compound, (C(6)H(14)N(2))[Fe(C(2)O(4))Cl(2)(H(2)O)(2)]Cl, all ions are situated on twofold rotational axes. The Fe(III) ion is coordinated by two O atoms from a chelating oxalate ligand, two water mol­ecules and two chloride anions in a distorted octa­hedral geometry. Inter­molecular N—...

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Detalles Bibliográficos
Autor principal: Cai, Ying
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977407/
https://www.ncbi.nlm.nih.gov/pubmed/21583342
http://dx.doi.org/10.1107/S1600536809025628
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author Cai, Ying
author_facet Cai, Ying
author_sort Cai, Ying
collection PubMed
description In the title compound, (C(6)H(14)N(2))[Fe(C(2)O(4))Cl(2)(H(2)O)(2)]Cl, all ions are situated on twofold rotational axes. The Fe(III) ion is coordinated by two O atoms from a chelating oxalate ligand, two water mol­ecules and two chloride anions in a distorted octa­hedral geometry. Inter­molecular N—H⋯O, O—H⋯O and O—H⋯Cl hydrogen bonds form an extensive three-dimensional network which consolidates the crystal packing.
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spelling pubmed-29774072010-12-30 1,4-Diazo­niabicyclo­[2.2.2]octane diaqua­dichlorido­(oxalato-κ(2) O,O′)iron(III) chloride Cai, Ying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(6)H(14)N(2))[Fe(C(2)O(4))Cl(2)(H(2)O)(2)]Cl, all ions are situated on twofold rotational axes. The Fe(III) ion is coordinated by two O atoms from a chelating oxalate ligand, two water mol­ecules and two chloride anions in a distorted octa­hedral geometry. Inter­molecular N—H⋯O, O—H⋯O and O—H⋯Cl hydrogen bonds form an extensive three-dimensional network which consolidates the crystal packing. International Union of Crystallography 2009-07-08 /pmc/articles/PMC2977407/ /pubmed/21583342 http://dx.doi.org/10.1107/S1600536809025628 Text en © Ying Cai 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cai, Ying
1,4-Diazo­niabicyclo­[2.2.2]octane diaqua­dichlorido­(oxalato-κ(2) O,O′)iron(III) chloride
title 1,4-Diazo­niabicyclo­[2.2.2]octane diaqua­dichlorido­(oxalato-κ(2) O,O′)iron(III) chloride
title_full 1,4-Diazo­niabicyclo­[2.2.2]octane diaqua­dichlorido­(oxalato-κ(2) O,O′)iron(III) chloride
title_fullStr 1,4-Diazo­niabicyclo­[2.2.2]octane diaqua­dichlorido­(oxalato-κ(2) O,O′)iron(III) chloride
title_full_unstemmed 1,4-Diazo­niabicyclo­[2.2.2]octane diaqua­dichlorido­(oxalato-κ(2) O,O′)iron(III) chloride
title_short 1,4-Diazo­niabicyclo­[2.2.2]octane diaqua­dichlorido­(oxalato-κ(2) O,O′)iron(III) chloride
title_sort 1,4-diazo­niabicyclo­[2.2.2]octane diaqua­dichlorido­(oxalato-κ(2) o,o′)iron(iii) chloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977407/
https://www.ncbi.nlm.nih.gov/pubmed/21583342
http://dx.doi.org/10.1107/S1600536809025628
work_keys_str_mv AT caiying 14diazoniabicyclo222octanediaquadichloridooxalatok2ooironiiichloride

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