4,4′-Di-tert-butyl-2,2′-bipyridine

In the title compound, C(18)H(24)N(2), the mol­ecular unit adopts a trans conformation around the central C—C bond [N—C—C—N torsion angle of 179.2 (3)°], with the two aromatic rings almost coplanar [dihedral angle of only 0.70 (4)°]. The crystal packing is driven by co-operative contacts involving w...

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Detalles Bibliográficos
Autores principales: Amarante, Tatiana R., Figueiredo, Sónia, Lopes, André D., Gonçalves, Isabel S., Almeida Paz, Filipe A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977408/
https://www.ncbi.nlm.nih.gov/pubmed/21583710
http://dx.doi.org/10.1107/S1600536809029109
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author Amarante, Tatiana R.
Figueiredo, Sónia
Lopes, André D.
Gonçalves, Isabel S.
Almeida Paz, Filipe A.
author_facet Amarante, Tatiana R.
Figueiredo, Sónia
Lopes, André D.
Gonçalves, Isabel S.
Almeida Paz, Filipe A.
author_sort Amarante, Tatiana R.
collection PubMed
description In the title compound, C(18)H(24)N(2), the mol­ecular unit adopts a trans conformation around the central C—C bond [N—C—C—N torsion angle of 179.2 (3)°], with the two aromatic rings almost coplanar [dihedral angle of only 0.70 (4)°]. The crystal packing is driven by co-operative contacts involving weak C—H⋯N and C—H⋯π inter­actions, and also the need to fill effectively the available space.
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spelling pubmed-29774082010-12-30 4,4′-Di-tert-butyl-2,2′-bipyridine Amarante, Tatiana R. Figueiredo, Sónia Lopes, André D. Gonçalves, Isabel S. Almeida Paz, Filipe A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(24)N(2), the mol­ecular unit adopts a trans conformation around the central C—C bond [N—C—C—N torsion angle of 179.2 (3)°], with the two aromatic rings almost coplanar [dihedral angle of only 0.70 (4)°]. The crystal packing is driven by co-operative contacts involving weak C—H⋯N and C—H⋯π inter­actions, and also the need to fill effectively the available space. International Union of Crystallography 2009-07-31 /pmc/articles/PMC2977408/ /pubmed/21583710 http://dx.doi.org/10.1107/S1600536809029109 Text en © Amarante et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Amarante, Tatiana R.
Figueiredo, Sónia
Lopes, André D.
Gonçalves, Isabel S.
Almeida Paz, Filipe A.
4,4′-Di-tert-butyl-2,2′-bipyridine
title 4,4′-Di-tert-butyl-2,2′-bipyridine
title_full 4,4′-Di-tert-butyl-2,2′-bipyridine
title_fullStr 4,4′-Di-tert-butyl-2,2′-bipyridine
title_full_unstemmed 4,4′-Di-tert-butyl-2,2′-bipyridine
title_short 4,4′-Di-tert-butyl-2,2′-bipyridine
title_sort 4,4′-di-tert-butyl-2,2′-bipyridine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977408/
https://www.ncbi.nlm.nih.gov/pubmed/21583710
http://dx.doi.org/10.1107/S1600536809029109
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