Methyl (E)-N′-[1-(2,4-dihydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate

The mol­ecule of the title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the methyl hydrazinecarboxyl­ate plane is 3.01 (6)°. An intra­molecular O—H⋯N hydrogen bond is observed. In the crystal, mol­ecules are...

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Detalles Bibliográficos
Autores principales: Lv, Lu-Ping, Li, Wei-Wei, Yu, Wen-Bo, Yu, Tie-Ming, Hu, Xian-Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977410/
https://www.ncbi.nlm.nih.gov/pubmed/21583586
http://dx.doi.org/10.1107/S1600536809027317
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author Lv, Lu-Ping
Li, Wei-Wei
Yu, Wen-Bo
Yu, Tie-Ming
Hu, Xian-Chao
author_facet Lv, Lu-Ping
Li, Wei-Wei
Yu, Wen-Bo
Yu, Tie-Ming
Hu, Xian-Chao
author_sort Lv, Lu-Ping
collection PubMed
description The mol­ecule of the title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the methyl hydrazinecarboxyl­ate plane is 3.01 (6)°. An intra­molecular O—H⋯N hydrogen bond is observed. In the crystal, mol­ecules are linked into a two-dimensional network parallel to (10[Image: see text]) by O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds.
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spelling pubmed-29774102010-12-30 Methyl (E)-N′-[1-(2,4-dihydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate Lv, Lu-Ping Li, Wei-Wei Yu, Wen-Bo Yu, Tie-Ming Hu, Xian-Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the methyl hydrazinecarboxyl­ate plane is 3.01 (6)°. An intra­molecular O—H⋯N hydrogen bond is observed. In the crystal, mol­ecules are linked into a two-dimensional network parallel to (10[Image: see text]) by O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977410/ /pubmed/21583586 http://dx.doi.org/10.1107/S1600536809027317 Text en © Lv et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lv, Lu-Ping
Li, Wei-Wei
Yu, Wen-Bo
Yu, Tie-Ming
Hu, Xian-Chao
Methyl (E)-N′-[1-(2,4-dihydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title Methyl (E)-N′-[1-(2,4-dihydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title_full Methyl (E)-N′-[1-(2,4-dihydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title_fullStr Methyl (E)-N′-[1-(2,4-dihydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title_full_unstemmed Methyl (E)-N′-[1-(2,4-dihydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title_short Methyl (E)-N′-[1-(2,4-dihydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title_sort methyl (e)-n′-[1-(2,4-dihydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977410/
https://www.ncbi.nlm.nih.gov/pubmed/21583586
http://dx.doi.org/10.1107/S1600536809027317
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