N′-(3,4-Dimethoxy­benzyl­idene)acetohydrazide

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In the title mol­ecule, C(11)H(14)N(2)O(3), the acetohydrazide group is planar 0.084 (1) Å and forms a dihedral angle of 19.7 (1)° with the benzene ring. One of the meth­oxy groups is coplanar with the attached benzene ring within 0.052 (3) Å, whereas the other is slightly twisted [C—O—C—C = 6.3 (3)...

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Autores principales: Lv, Lu-Ping, Yu, Tie-Ming, Yu, Wen-Bo, Li, Wei-Wei, Hu, Xian-Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977411/
https://www.ncbi.nlm.nih.gov/pubmed/21583663
http://dx.doi.org/10.1107/S1600536809027366
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author Lv, Lu-Ping
Yu, Tie-Ming
Yu, Wen-Bo
Li, Wei-Wei
Hu, Xian-Chao
author_facet Lv, Lu-Ping
Yu, Tie-Ming
Yu, Wen-Bo
Li, Wei-Wei
Hu, Xian-Chao
author_sort Lv, Lu-Ping
collection PubMed
description In the title mol­ecule, C(11)H(14)N(2)O(3), the acetohydrazide group is planar 0.084 (1) Å and forms a dihedral angle of 19.7 (1)° with the benzene ring. One of the meth­oxy groups is coplanar with the attached benzene ring within 0.052 (3) Å, whereas the other is slightly twisted [C—O—C—C = 6.3 (3)°]. The mol­ecule adopts a trans configuration with respect to the C=N bond. In the crystal, the mol­ecules are linked into chains along the a axis by N—H⋯O hydrogen bonds and the chains are cross-linked into a three-dimensional network by C—H⋯O hydrogen bonds.
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spelling pubmed-29774112010-12-30 N′-(3,4-Dimethoxy­benzyl­idene)acetohydrazide Lv, Lu-Ping Yu, Tie-Ming Yu, Wen-Bo Li, Wei-Wei Hu, Xian-Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(11)H(14)N(2)O(3), the acetohydrazide group is planar 0.084 (1) Å and forms a dihedral angle of 19.7 (1)° with the benzene ring. One of the meth­oxy groups is coplanar with the attached benzene ring within 0.052 (3) Å, whereas the other is slightly twisted [C—O—C—C = 6.3 (3)°]. The mol­ecule adopts a trans configuration with respect to the C=N bond. In the crystal, the mol­ecules are linked into chains along the a axis by N—H⋯O hydrogen bonds and the chains are cross-linked into a three-dimensional network by C—H⋯O hydrogen bonds. International Union of Crystallography 2009-07-25 /pmc/articles/PMC2977411/ /pubmed/21583663 http://dx.doi.org/10.1107/S1600536809027366 Text en © Lv et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lv, Lu-Ping
Yu, Tie-Ming
Yu, Wen-Bo
Li, Wei-Wei
Hu, Xian-Chao
N′-(3,4-Dimethoxy­benzyl­idene)acetohydrazide
title N′-(3,4-Dimethoxy­benzyl­idene)acetohydrazide
title_full N′-(3,4-Dimethoxy­benzyl­idene)acetohydrazide
title_fullStr N′-(3,4-Dimethoxy­benzyl­idene)acetohydrazide
title_full_unstemmed N′-(3,4-Dimethoxy­benzyl­idene)acetohydrazide
title_short N′-(3,4-Dimethoxy­benzyl­idene)acetohydrazide
title_sort n′-(3,4-dimethoxy­benzyl­idene)acetohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977411/
https://www.ncbi.nlm.nih.gov/pubmed/21583663
http://dx.doi.org/10.1107/S1600536809027366
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