2-Bromo-N′-[(Z)-2-bromo­benzyl­idene]-5-methoxy­benzohydrazide

In the title compound, C(15)H(12)Br(2)N(2)O(2), the mol­ecule adopts an E conformation about the C=N double bond and a transoid conformation about the central N—N bond, with a C(=O)—N—N—C(H) dihedral angle of 169.4 (4)°. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds, leading to C(4)...

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Detalles Bibliográficos
Autores principales: Li, Hongqi, Sarojini, B. K., Narayana, B., Yathirajan, H. S., Harrison, William T. A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977412/
https://www.ncbi.nlm.nih.gov/pubmed/21583461
http://dx.doi.org/10.1107/S1600536809024921
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author Li, Hongqi
Sarojini, B. K.
Narayana, B.
Yathirajan, H. S.
Harrison, William T. A.
author_facet Li, Hongqi
Sarojini, B. K.
Narayana, B.
Yathirajan, H. S.
Harrison, William T. A.
author_sort Li, Hongqi
collection PubMed
description In the title compound, C(15)H(12)Br(2)N(2)O(2), the mol­ecule adopts an E conformation about the C=N double bond and a transoid conformation about the central N—N bond, with a C(=O)—N—N—C(H) dihedral angle of 169.4 (4)°. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds, leading to C(4) chains. The packing also features slipped π–π stacking inter­actions, with a centroid–centroid separation of 3.838 (3) Å and a slippage of 1.19 Å.
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spelling pubmed-29774122010-12-30 2-Bromo-N′-[(Z)-2-bromo­benzyl­idene]-5-methoxy­benzohydrazide Li, Hongqi Sarojini, B. K. Narayana, B. Yathirajan, H. S. Harrison, William T. A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(12)Br(2)N(2)O(2), the mol­ecule adopts an E conformation about the C=N double bond and a transoid conformation about the central N—N bond, with a C(=O)—N—N—C(H) dihedral angle of 169.4 (4)°. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds, leading to C(4) chains. The packing also features slipped π–π stacking inter­actions, with a centroid–centroid separation of 3.838 (3) Å and a slippage of 1.19 Å. International Union of Crystallography 2009-07-04 /pmc/articles/PMC2977412/ /pubmed/21583461 http://dx.doi.org/10.1107/S1600536809024921 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Hongqi
Sarojini, B. K.
Narayana, B.
Yathirajan, H. S.
Harrison, William T. A.
2-Bromo-N′-[(Z)-2-bromo­benzyl­idene]-5-methoxy­benzohydrazide
title 2-Bromo-N′-[(Z)-2-bromo­benzyl­idene]-5-methoxy­benzohydrazide
title_full 2-Bromo-N′-[(Z)-2-bromo­benzyl­idene]-5-methoxy­benzohydrazide
title_fullStr 2-Bromo-N′-[(Z)-2-bromo­benzyl­idene]-5-methoxy­benzohydrazide
title_full_unstemmed 2-Bromo-N′-[(Z)-2-bromo­benzyl­idene]-5-methoxy­benzohydrazide
title_short 2-Bromo-N′-[(Z)-2-bromo­benzyl­idene]-5-methoxy­benzohydrazide
title_sort 2-bromo-n′-[(z)-2-bromo­benzyl­idene]-5-methoxy­benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977412/
https://www.ncbi.nlm.nih.gov/pubmed/21583461
http://dx.doi.org/10.1107/S1600536809024921
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AT yathirajanhs 2bromonz2bromobenzylidene5methoxybenzohydrazide
AT harrisonwilliamta 2bromonz2bromobenzylidene5methoxybenzohydrazide

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