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Tetra-μ-acetato-bis{[9-(pyrazin-2-yl)-9H-carbazole]copper(II)}
The title complex, [Cu(2)(CH(3)COO)(4)(C(16)H(11)N(3))(2)], lies on an inversion centre, with four acetate ligands bridging two symmetry-related Cu(II) ions and two monodentate 9-(pyrazin-2-yl)-9H-carbazole ligands coordinating each Cu(II) ion via the N atoms of the pyrazine rings, forming slightly...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977416/ https://www.ncbi.nlm.nih.gov/pubmed/21583385 http://dx.doi.org/10.1107/S160053680902710X |
| _version_ | 1782191103051563008 |
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| author | Li, Jin Min |
| author_facet | Li, Jin Min |
| author_sort | Li, Jin Min |
| collection | PubMed |
| description | The title complex, [Cu(2)(CH(3)COO)(4)(C(16)H(11)N(3))(2)], lies on an inversion centre, with four acetate ligands bridging two symmetry-related Cu(II) ions and two monodentate 9-(pyrazin-2-yl)-9H-carbazole ligands coordinating each Cu(II) ion via the N atoms of the pyrazine rings, forming slightly distorted square-pyramidal geometries. There are weak π–π stacking interactions between the pyrrole rings of symmetry-related molecules, with a centroid-to-centroid distance of 3.692 (2) Å. |
| format | Text |
| id | pubmed-2977416 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29774162010-12-30 Tetra-μ-acetato-bis{[9-(pyrazin-2-yl)-9H-carbazole]copper(II)} Li, Jin Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(2)(CH(3)COO)(4)(C(16)H(11)N(3))(2)], lies on an inversion centre, with four acetate ligands bridging two symmetry-related Cu(II) ions and two monodentate 9-(pyrazin-2-yl)-9H-carbazole ligands coordinating each Cu(II) ion via the N atoms of the pyrazine rings, forming slightly distorted square-pyramidal geometries. There are weak π–π stacking interactions between the pyrrole rings of symmetry-related molecules, with a centroid-to-centroid distance of 3.692 (2) Å. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977416/ /pubmed/21583385 http://dx.doi.org/10.1107/S160053680902710X Text en © Jin Min Li 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Jin Min Tetra-μ-acetato-bis{[9-(pyrazin-2-yl)-9H-carbazole]copper(II)} |
| title | Tetra-μ-acetato-bis{[9-(pyrazin-2-yl)-9H-carbazole]copper(II)} |
| title_full | Tetra-μ-acetato-bis{[9-(pyrazin-2-yl)-9H-carbazole]copper(II)} |
| title_fullStr | Tetra-μ-acetato-bis{[9-(pyrazin-2-yl)-9H-carbazole]copper(II)} |
| title_full_unstemmed | Tetra-μ-acetato-bis{[9-(pyrazin-2-yl)-9H-carbazole]copper(II)} |
| title_short | Tetra-μ-acetato-bis{[9-(pyrazin-2-yl)-9H-carbazole]copper(II)} |
| title_sort | tetra-μ-acetato-bis{[9-(pyrazin-2-yl)-9h-carbazole]copper(ii)} |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977416/ https://www.ncbi.nlm.nih.gov/pubmed/21583385 http://dx.doi.org/10.1107/S160053680902710X |
| work_keys_str_mv | AT lijinmin tetramacetatobis9pyrazin2yl9hcarbazolecopperii |