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Nonapiperidinium monohydrogen decavanadate tetranitrate
The title compound, (C(5)H(12)N)(9)[HV(10)O(28)](NO(3))(4), contains a monoprotonated decavanadate polyanion which lies on an inversion center. All the piperidinium cations adopt chair conformations. In the crystal structure, intermolecular N—H⋯O hydrogen bonds form chains along [001]. As well as...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977420/ https://www.ncbi.nlm.nih.gov/pubmed/21583402 http://dx.doi.org/10.1107/S1600536809026555 |
Sumario: | The title compound, (C(5)H(12)N)(9)[HV(10)O(28)](NO(3))(4), contains a monoprotonated decavanadate polyanion which lies on an inversion center. All the piperidinium cations adopt chair conformations. In the crystal structure, intermolecular N—H⋯O hydrogen bonds form chains along [001]. As well as half of a polyanion, the asymmetric unit contains one full and two half-occupancy nitrate ions and four full occupancy and one half-occupancy piperidinium cations; the half-occupancy piperidinium cation is disordered over two general sites with occupancies of 0.32 and 0.18, and is, in turn, disordered over an inversion center. |
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