Cargando…

Nonapiperidinium monohydrogen deca­vanadate tetra­nitrate

The title compound, (C(5)H(12)N)(9)[HV(10)O(28)](NO(3))(4), contains a monoprotonated deca­vanadate polyanion which lies on an inversion center. All the piperidinium cations adopt chair conformations. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds form chains along [001]. As well as...

Descripción completa

Detalles Bibliográficos
Autores principales: Graia, Mohsen, Ksiksi, Regaya, Driss, Ahmed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977420/
https://www.ncbi.nlm.nih.gov/pubmed/21583402
http://dx.doi.org/10.1107/S1600536809026555
Descripción
Sumario:The title compound, (C(5)H(12)N)(9)[HV(10)O(28)](NO(3))(4), contains a monoprotonated deca­vanadate polyanion which lies on an inversion center. All the piperidinium cations adopt chair conformations. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds form chains along [001]. As well as half of a polyanion, the asymmetric unit contains one full and two half-occupancy nitrate ions and four full occupancy and one half-occupancy piperidinium cations; the half-occupancy piperidinium cation is disordered over two general sites with occupancies of 0.32 and 0.18, and is, in turn, disordered over an inversion center.