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Nonapiperidinium monohydrogen deca­vanadate tetra­nitrate

The title compound, (C(5)H(12)N)(9)[HV(10)O(28)](NO(3))(4), contains a monoprotonated deca­vanadate polyanion which lies on an inversion center. All the piperidinium cations adopt chair conformations. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds form chains along [001]. As well as...

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Detalles Bibliográficos
Autores principales: Graia, Mohsen, Ksiksi, Regaya, Driss, Ahmed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977420/
https://www.ncbi.nlm.nih.gov/pubmed/21583402
http://dx.doi.org/10.1107/S1600536809026555
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author Graia, Mohsen
Ksiksi, Regaya
Driss, Ahmed
author_facet Graia, Mohsen
Ksiksi, Regaya
Driss, Ahmed
author_sort Graia, Mohsen
collection PubMed
description The title compound, (C(5)H(12)N)(9)[HV(10)O(28)](NO(3))(4), contains a monoprotonated deca­vanadate polyanion which lies on an inversion center. All the piperidinium cations adopt chair conformations. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds form chains along [001]. As well as half of a polyanion, the asymmetric unit contains one full and two half-occupancy nitrate ions and four full occupancy and one half-occupancy piperidinium cations; the half-occupancy piperidinium cation is disordered over two general sites with occupancies of 0.32 and 0.18, and is, in turn, disordered over an inversion center.
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spelling pubmed-29774202010-12-30 Nonapiperidinium monohydrogen deca­vanadate tetra­nitrate Graia, Mohsen Ksiksi, Regaya Driss, Ahmed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(5)H(12)N)(9)[HV(10)O(28)](NO(3))(4), contains a monoprotonated deca­vanadate polyanion which lies on an inversion center. All the piperidinium cations adopt chair conformations. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds form chains along [001]. As well as half of a polyanion, the asymmetric unit contains one full and two half-occupancy nitrate ions and four full occupancy and one half-occupancy piperidinium cations; the half-occupancy piperidinium cation is disordered over two general sites with occupancies of 0.32 and 0.18, and is, in turn, disordered over an inversion center. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977420/ /pubmed/21583402 http://dx.doi.org/10.1107/S1600536809026555 Text en © Graia et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Graia, Mohsen
Ksiksi, Regaya
Driss, Ahmed
Nonapiperidinium monohydrogen deca­vanadate tetra­nitrate
title Nonapiperidinium monohydrogen deca­vanadate tetra­nitrate
title_full Nonapiperidinium monohydrogen deca­vanadate tetra­nitrate
title_fullStr Nonapiperidinium monohydrogen deca­vanadate tetra­nitrate
title_full_unstemmed Nonapiperidinium monohydrogen deca­vanadate tetra­nitrate
title_short Nonapiperidinium monohydrogen deca­vanadate tetra­nitrate
title_sort nonapiperidinium monohydrogen deca­vanadate tetra­nitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977420/
https://www.ncbi.nlm.nih.gov/pubmed/21583402
http://dx.doi.org/10.1107/S1600536809026555
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