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Nonapiperidinium monohydrogen decavanadate tetranitrate
The title compound, (C(5)H(12)N)(9)[HV(10)O(28)](NO(3))(4), contains a monoprotonated decavanadate polyanion which lies on an inversion center. All the piperidinium cations adopt chair conformations. In the crystal structure, intermolecular N—H⋯O hydrogen bonds form chains along [001]. As well as...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977420/ https://www.ncbi.nlm.nih.gov/pubmed/21583402 http://dx.doi.org/10.1107/S1600536809026555 |
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author | Graia, Mohsen Ksiksi, Regaya Driss, Ahmed |
author_facet | Graia, Mohsen Ksiksi, Regaya Driss, Ahmed |
author_sort | Graia, Mohsen |
collection | PubMed |
description | The title compound, (C(5)H(12)N)(9)[HV(10)O(28)](NO(3))(4), contains a monoprotonated decavanadate polyanion which lies on an inversion center. All the piperidinium cations adopt chair conformations. In the crystal structure, intermolecular N—H⋯O hydrogen bonds form chains along [001]. As well as half of a polyanion, the asymmetric unit contains one full and two half-occupancy nitrate ions and four full occupancy and one half-occupancy piperidinium cations; the half-occupancy piperidinium cation is disordered over two general sites with occupancies of 0.32 and 0.18, and is, in turn, disordered over an inversion center. |
format | Text |
id | pubmed-2977420 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29774202010-12-30 Nonapiperidinium monohydrogen decavanadate tetranitrate Graia, Mohsen Ksiksi, Regaya Driss, Ahmed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(5)H(12)N)(9)[HV(10)O(28)](NO(3))(4), contains a monoprotonated decavanadate polyanion which lies on an inversion center. All the piperidinium cations adopt chair conformations. In the crystal structure, intermolecular N—H⋯O hydrogen bonds form chains along [001]. As well as half of a polyanion, the asymmetric unit contains one full and two half-occupancy nitrate ions and four full occupancy and one half-occupancy piperidinium cations; the half-occupancy piperidinium cation is disordered over two general sites with occupancies of 0.32 and 0.18, and is, in turn, disordered over an inversion center. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977420/ /pubmed/21583402 http://dx.doi.org/10.1107/S1600536809026555 Text en © Graia et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Graia, Mohsen Ksiksi, Regaya Driss, Ahmed Nonapiperidinium monohydrogen decavanadate tetranitrate |
title | Nonapiperidinium monohydrogen decavanadate tetranitrate |
title_full | Nonapiperidinium monohydrogen decavanadate tetranitrate |
title_fullStr | Nonapiperidinium monohydrogen decavanadate tetranitrate |
title_full_unstemmed | Nonapiperidinium monohydrogen decavanadate tetranitrate |
title_short | Nonapiperidinium monohydrogen decavanadate tetranitrate |
title_sort | nonapiperidinium monohydrogen decavanadate tetranitrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977420/ https://www.ncbi.nlm.nih.gov/pubmed/21583402 http://dx.doi.org/10.1107/S1600536809026555 |
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