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trans-Dibromidobis(triphenylphosphine-κP)palladium(II) chloroform monosolvate
The Pd(II) atom in the title compound, [PdBr(2){P(C(6)H(5))(3)}(2)]·CHCl(3), lies on a twofold rotation axis and is coordinated in a distorted square-planar geometry by two P atoms from two triphenylphosphine ligands and by two Br atoms in a trans arrangement. The chloroform solvent molecule is e...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977421/ https://www.ncbi.nlm.nih.gov/pubmed/21583391 http://dx.doi.org/10.1107/S1600536809027408 |
| _version_ | 1782191104224919552 |
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| author | Lo, Kong Mun Ng, Seik Weng |
| author_facet | Lo, Kong Mun Ng, Seik Weng |
| author_sort | Lo, Kong Mun |
| collection | PubMed |
| description | The Pd(II) atom in the title compound, [PdBr(2){P(C(6)H(5))(3)}(2)]·CHCl(3), lies on a twofold rotation axis and is coordinated in a distorted square-planar geometry by two P atoms from two triphenylphosphine ligands and by two Br atoms in a trans arrangement. The chloroform solvent molecule is equally disordered about another twofold rotation axis. |
| format | Text |
| id | pubmed-2977421 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29774212010-12-30 trans-Dibromidobis(triphenylphosphine-κP)palladium(II) chloroform monosolvate Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pd(II) atom in the title compound, [PdBr(2){P(C(6)H(5))(3)}(2)]·CHCl(3), lies on a twofold rotation axis and is coordinated in a distorted square-planar geometry by two P atoms from two triphenylphosphine ligands and by two Br atoms in a trans arrangement. The chloroform solvent molecule is equally disordered about another twofold rotation axis. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977421/ /pubmed/21583391 http://dx.doi.org/10.1107/S1600536809027408 Text en © Lo and Ng 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lo, Kong Mun Ng, Seik Weng trans-Dibromidobis(triphenylphosphine-κP)palladium(II) chloroform monosolvate |
| title |
trans-Dibromidobis(triphenylphosphine-κP)palladium(II) chloroform monosolvate |
| title_full |
trans-Dibromidobis(triphenylphosphine-κP)palladium(II) chloroform monosolvate |
| title_fullStr |
trans-Dibromidobis(triphenylphosphine-κP)palladium(II) chloroform monosolvate |
| title_full_unstemmed |
trans-Dibromidobis(triphenylphosphine-κP)palladium(II) chloroform monosolvate |
| title_short |
trans-Dibromidobis(triphenylphosphine-κP)palladium(II) chloroform monosolvate |
| title_sort | trans-dibromidobis(triphenylphosphine-κp)palladium(ii) chloroform monosolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977421/ https://www.ncbi.nlm.nih.gov/pubmed/21583391 http://dx.doi.org/10.1107/S1600536809027408 |
| work_keys_str_mv | AT lokongmun transdibromidobistriphenylphosphinekppalladiumiichloroformmonosolvate AT ngseikweng transdibromidobistriphenylphosphinekppalladiumiichloroformmonosolvate |