1,15:21,35-Bis(oxydiethyl­ene)-5,8,11,18,25,28,31,38-octa­oxa-1,15,21,35-tetra­azacyclo­tetra­decane-16,20,36,40-tetra­one–benzene (1/2): a macrotricyclic tetra­lactam

The macrotricyclic title compound, C(36)H(64)N(4)O(14)·2C(6)H(6), is located on a crystallographic center of symmetry. The mol­ecule has four tertiary amide bridgehead atoms and consists of two unsymmetrical 20-membered diaza­tetra­oxamacrocycles (N(2)O(4) donor atom set) connected through the N ato...

Descripción completa

Detalles Bibliográficos
Autores principales: Smith, Gary L. N., Nguyen, Tam, Powell, Douglas R., Taylor, Richard W.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977422/
https://www.ncbi.nlm.nih.gov/pubmed/21583610
http://dx.doi.org/10.1107/S1600536809026531
_version_ 1782191104462946304
author Smith, Gary L. N.
Nguyen, Tam
Powell, Douglas R.
Taylor, Richard W.
author_facet Smith, Gary L. N.
Nguyen, Tam
Powell, Douglas R.
Taylor, Richard W.
author_sort Smith, Gary L. N.
collection PubMed
description The macrotricyclic title compound, C(36)H(64)N(4)O(14)·2C(6)H(6), is located on a crystallographic center of symmetry. The mol­ecule has four tertiary amide bridgehead atoms and consists of two unsymmetrical 20-membered diaza­tetra­oxamacrocycles (N(2)O(4) donor atom set) connected through the N atoms by two lateral oxydiethyl­ene bridges. The bridging subunits, together with the short bridging strand (NCCOCCN) from each monocycle, define a 24-membered ring (N(4)O(4) donor atom set) that forms a central cavity.
format Text
id pubmed-2977422
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29774222010-12-30 1,15:21,35-Bis(oxydiethyl­ene)-5,8,11,18,25,28,31,38-octa­oxa-1,15,21,35-tetra­azacyclo­tetra­decane-16,20,36,40-tetra­one–benzene (1/2): a macrotricyclic tetra­lactam Smith, Gary L. N. Nguyen, Tam Powell, Douglas R. Taylor, Richard W. Acta Crystallogr Sect E Struct Rep Online Organic Papers The macrotricyclic title compound, C(36)H(64)N(4)O(14)·2C(6)H(6), is located on a crystallographic center of symmetry. The mol­ecule has four tertiary amide bridgehead atoms and consists of two unsymmetrical 20-membered diaza­tetra­oxamacrocycles (N(2)O(4) donor atom set) connected through the N atoms by two lateral oxydiethyl­ene bridges. The bridging subunits, together with the short bridging strand (NCCOCCN) from each monocycle, define a 24-membered ring (N(4)O(4) donor atom set) that forms a central cavity. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977422/ /pubmed/21583610 http://dx.doi.org/10.1107/S1600536809026531 Text en © Smith et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Smith, Gary L. N.
Nguyen, Tam
Powell, Douglas R.
Taylor, Richard W.
1,15:21,35-Bis(oxydiethyl­ene)-5,8,11,18,25,28,31,38-octa­oxa-1,15,21,35-tetra­azacyclo­tetra­decane-16,20,36,40-tetra­one–benzene (1/2): a macrotricyclic tetra­lactam
title 1,15:21,35-Bis(oxydiethyl­ene)-5,8,11,18,25,28,31,38-octa­oxa-1,15,21,35-tetra­azacyclo­tetra­decane-16,20,36,40-tetra­one–benzene (1/2): a macrotricyclic tetra­lactam
title_full 1,15:21,35-Bis(oxydiethyl­ene)-5,8,11,18,25,28,31,38-octa­oxa-1,15,21,35-tetra­azacyclo­tetra­decane-16,20,36,40-tetra­one–benzene (1/2): a macrotricyclic tetra­lactam
title_fullStr 1,15:21,35-Bis(oxydiethyl­ene)-5,8,11,18,25,28,31,38-octa­oxa-1,15,21,35-tetra­azacyclo­tetra­decane-16,20,36,40-tetra­one–benzene (1/2): a macrotricyclic tetra­lactam
title_full_unstemmed 1,15:21,35-Bis(oxydiethyl­ene)-5,8,11,18,25,28,31,38-octa­oxa-1,15,21,35-tetra­azacyclo­tetra­decane-16,20,36,40-tetra­one–benzene (1/2): a macrotricyclic tetra­lactam
title_short 1,15:21,35-Bis(oxydiethyl­ene)-5,8,11,18,25,28,31,38-octa­oxa-1,15,21,35-tetra­azacyclo­tetra­decane-16,20,36,40-tetra­one–benzene (1/2): a macrotricyclic tetra­lactam
title_sort 1,15:21,35-bis(oxydiethyl­ene)-5,8,11,18,25,28,31,38-octa­oxa-1,15,21,35-tetra­azacyclo­tetra­decane-16,20,36,40-tetra­one–benzene (1/2): a macrotricyclic tetra­lactam
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977422/
https://www.ncbi.nlm.nih.gov/pubmed/21583610
http://dx.doi.org/10.1107/S1600536809026531
work_keys_str_mv AT smithgaryln 1152135bisoxydiethylene58111825283138octaoxa1152135tetraazacyclotetradecane16203640tetraonebenzene12amacrotricyclictetralactam
AT nguyentam 1152135bisoxydiethylene58111825283138octaoxa1152135tetraazacyclotetradecane16203640tetraonebenzene12amacrotricyclictetralactam
AT powelldouglasr 1152135bisoxydiethylene58111825283138octaoxa1152135tetraazacyclotetradecane16203640tetraonebenzene12amacrotricyclictetralactam
AT taylorrichardw 1152135bisoxydiethylene58111825283138octaoxa1152135tetraazacyclotetradecane16203640tetraonebenzene12amacrotricyclictetralactam

Ejemplares similares