A new coordination tetra­mer of copper(I) iodide and benzyl­dimethyl­amine: tetra-μ(3)-iodido-tetra­kis[(benzyl­dimethyl­amine-κN)copper(I)]

The title compound, [Cu(4)I(4)(C(9)H(13)N)(4)], has a distorted cubane-like [Cu(4)I(4)] core structure. Each Cu(I) atom is tetra­hedrally coordinated by three I atoms and one N atom of an benzyl­dimethyl­amine ligand. Each I atom acts as a μ(3)-ligand, linking three Cu(I) atoms. The Cu—I bond distan...

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Detalles Bibliográficos
Autores principales: Yang, Shuying, Li, Yuebao, Cui, Yujie, Pan, Jianguo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977424/
https://www.ncbi.nlm.nih.gov/pubmed/21583366
http://dx.doi.org/10.1107/S1600536809026208
Descripción
Sumario:The title compound, [Cu(4)I(4)(C(9)H(13)N)(4)], has a distorted cubane-like [Cu(4)I(4)] core structure. Each Cu(I) atom is tetra­hedrally coordinated by three I atoms and one N atom of an benzyl­dimethyl­amine ligand. Each I atom acts as a μ(3)-ligand, linking three Cu(I) atoms. The Cu—I bond distances vary between 2.6328 (7) and 2.7121 (6) Å, while the Cu—N bond distances vary between 2.107 (3) and 2.122 (3) Å.

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