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A new coordination tetramer of copper(I) iodide and benzyldimethylamine: tetra-μ(3)-iodido-tetrakis[(benzyldimethylamine-κN)copper(I)]
The title compound, [Cu(4)I(4)(C(9)H(13)N)(4)], has a distorted cubane-like [Cu(4)I(4)] core structure. Each Cu(I) atom is tetrahedrally coordinated by three I atoms and one N atom of an benzyldimethylamine ligand. Each I atom acts as a μ(3)-ligand, linking three Cu(I) atoms. The Cu—I bond distan...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977424/ https://www.ncbi.nlm.nih.gov/pubmed/21583366 http://dx.doi.org/10.1107/S1600536809026208 |
| _version_ | 1782191104946339840 |
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| author | Yang, Shuying Li, Yuebao Cui, Yujie Pan, Jianguo |
| author_facet | Yang, Shuying Li, Yuebao Cui, Yujie Pan, Jianguo |
| author_sort | Yang, Shuying |
| collection | PubMed |
| description | The title compound, [Cu(4)I(4)(C(9)H(13)N)(4)], has a distorted cubane-like [Cu(4)I(4)] core structure. Each Cu(I) atom is tetrahedrally coordinated by three I atoms and one N atom of an benzyldimethylamine ligand. Each I atom acts as a μ(3)-ligand, linking three Cu(I) atoms. The Cu—I bond distances vary between 2.6328 (7) and 2.7121 (6) Å, while the Cu—N bond distances vary between 2.107 (3) and 2.122 (3) Å. |
| format | Text |
| id | pubmed-2977424 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29774242010-12-30 A new coordination tetramer of copper(I) iodide and benzyldimethylamine: tetra-μ(3)-iodido-tetrakis[(benzyldimethylamine-κN)copper(I)] Yang, Shuying Li, Yuebao Cui, Yujie Pan, Jianguo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(4)I(4)(C(9)H(13)N)(4)], has a distorted cubane-like [Cu(4)I(4)] core structure. Each Cu(I) atom is tetrahedrally coordinated by three I atoms and one N atom of an benzyldimethylamine ligand. Each I atom acts as a μ(3)-ligand, linking three Cu(I) atoms. The Cu—I bond distances vary between 2.6328 (7) and 2.7121 (6) Å, while the Cu—N bond distances vary between 2.107 (3) and 2.122 (3) Å. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977424/ /pubmed/21583366 http://dx.doi.org/10.1107/S1600536809026208 Text en © Yang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Yang, Shuying Li, Yuebao Cui, Yujie Pan, Jianguo A new coordination tetramer of copper(I) iodide and benzyldimethylamine: tetra-μ(3)-iodido-tetrakis[(benzyldimethylamine-κN)copper(I)] |
| title | A new coordination tetramer of copper(I) iodide and benzyldimethylamine: tetra-μ(3)-iodido-tetrakis[(benzyldimethylamine-κN)copper(I)] |
| title_full | A new coordination tetramer of copper(I) iodide and benzyldimethylamine: tetra-μ(3)-iodido-tetrakis[(benzyldimethylamine-κN)copper(I)] |
| title_fullStr | A new coordination tetramer of copper(I) iodide and benzyldimethylamine: tetra-μ(3)-iodido-tetrakis[(benzyldimethylamine-κN)copper(I)] |
| title_full_unstemmed | A new coordination tetramer of copper(I) iodide and benzyldimethylamine: tetra-μ(3)-iodido-tetrakis[(benzyldimethylamine-κN)copper(I)] |
| title_short | A new coordination tetramer of copper(I) iodide and benzyldimethylamine: tetra-μ(3)-iodido-tetrakis[(benzyldimethylamine-κN)copper(I)] |
| title_sort | new coordination tetramer of copper(i) iodide and benzyldimethylamine: tetra-μ(3)-iodido-tetrakis[(benzyldimethylamine-κn)copper(i)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977424/ https://www.ncbi.nlm.nih.gov/pubmed/21583366 http://dx.doi.org/10.1107/S1600536809026208 |
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