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N′-[(E)-(5-Bromo-2-hydroxyphenyl)(phenyl)methylidene]-4-chlorobenzohydrazide
The Schiff base, C(20)H(14)BrClN(2)O(2), displays a trans conformation with respect to the C=N double bond. The aromatic rings at either end of the –C(=O)–NH–N=C– fragment are nearly parallel [dihedral angle = 3.4 (5)°]. The hydroxy group forms an intramolecular hydrogen bond to the imino N atom....
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977427/ https://www.ncbi.nlm.nih.gov/pubmed/21583625 http://dx.doi.org/10.1107/S1600536809027949 |
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author | Zheng, Chang-Zheng Ji, Chang-You Chang, Xiu-Li |
author_facet | Zheng, Chang-Zheng Ji, Chang-You Chang, Xiu-Li |
author_sort | Zheng, Chang-Zheng |
collection | PubMed |
description | The Schiff base, C(20)H(14)BrClN(2)O(2), displays a trans conformation with respect to the C=N double bond. The aromatic rings at either end of the –C(=O)–NH–N=C– fragment are nearly parallel [dihedral angle = 3.4 (5)°]. The hydroxy group forms an intramolecular hydrogen bond to the imino N atom. |
format | Text |
id | pubmed-2977427 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29774272010-12-30 N′-[(E)-(5-Bromo-2-hydroxyphenyl)(phenyl)methylidene]-4-chlorobenzohydrazide Zheng, Chang-Zheng Ji, Chang-You Chang, Xiu-Li Acta Crystallogr Sect E Struct Rep Online Organic Papers The Schiff base, C(20)H(14)BrClN(2)O(2), displays a trans conformation with respect to the C=N double bond. The aromatic rings at either end of the –C(=O)–NH–N=C– fragment are nearly parallel [dihedral angle = 3.4 (5)°]. The hydroxy group forms an intramolecular hydrogen bond to the imino N atom. International Union of Crystallography 2009-07-22 /pmc/articles/PMC2977427/ /pubmed/21583625 http://dx.doi.org/10.1107/S1600536809027949 Text en © Zheng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zheng, Chang-Zheng Ji, Chang-You Chang, Xiu-Li N′-[(E)-(5-Bromo-2-hydroxyphenyl)(phenyl)methylidene]-4-chlorobenzohydrazide |
title |
N′-[(E)-(5-Bromo-2-hydroxyphenyl)(phenyl)methylidene]-4-chlorobenzohydrazide |
title_full |
N′-[(E)-(5-Bromo-2-hydroxyphenyl)(phenyl)methylidene]-4-chlorobenzohydrazide |
title_fullStr |
N′-[(E)-(5-Bromo-2-hydroxyphenyl)(phenyl)methylidene]-4-chlorobenzohydrazide |
title_full_unstemmed |
N′-[(E)-(5-Bromo-2-hydroxyphenyl)(phenyl)methylidene]-4-chlorobenzohydrazide |
title_short |
N′-[(E)-(5-Bromo-2-hydroxyphenyl)(phenyl)methylidene]-4-chlorobenzohydrazide |
title_sort | n′-[(e)-(5-bromo-2-hydroxyphenyl)(phenyl)methylidene]-4-chlorobenzohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977427/ https://www.ncbi.nlm.nih.gov/pubmed/21583625 http://dx.doi.org/10.1107/S1600536809027949 |
work_keys_str_mv | AT zhengchangzheng ne5bromo2hydroxyphenylphenylmethylidene4chlorobenzohydrazide AT jichangyou ne5bromo2hydroxyphenylphenylmethylidene4chlorobenzohydrazide AT changxiuli ne5bromo2hydroxyphenylphenylmethylidene4chlorobenzohydrazide |