N′-(4-Hydroxy­benzyl­idene)aceto­hydrazide monohydrate

In the title compound, C(9)H(10)N(2)O(2)·H(2)O, the mol­ecular skeleton of the acetohydrazide mol­ecule is nearly planar [within 0.014 (1) Å]. The mol­ecule adopts a trans configuration with respect to the C=N bond, while the side chain is slightly twisted away from the attached ring, forming a dihe...

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Detalles Bibliográficos
Autores principales: Lv, Lu-Ping, Yu, Tie-Ming, Yu, Wen-Bo, Li, Wei-Wei, Hu, Xian-Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977428/
https://www.ncbi.nlm.nih.gov/pubmed/21583678
http://dx.doi.org/10.1107/S160053680902892X
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author Lv, Lu-Ping
Yu, Tie-Ming
Yu, Wen-Bo
Li, Wei-Wei
Hu, Xian-Chao
author_facet Lv, Lu-Ping
Yu, Tie-Ming
Yu, Wen-Bo
Li, Wei-Wei
Hu, Xian-Chao
author_sort Lv, Lu-Ping
collection PubMed
description In the title compound, C(9)H(10)N(2)O(2)·H(2)O, the mol­ecular skeleton of the acetohydrazide mol­ecule is nearly planar [within 0.014 (1) Å]. The mol­ecule adopts a trans configuration with respect to the C=N bond, while the side chain is slightly twisted away from the attached ring, forming a dihedral angle of 9.975 (8)°. The crystal packing exhibits a three-dimensional network composed from alternating acetohydrazide mol­ecules and uncoordinated water mol­ecules, which inter­act via N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds. A C—H⋯π inter­action is also present.
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spelling pubmed-29774282010-12-30 N′-(4-Hydroxy­benzyl­idene)aceto­hydrazide monohydrate Lv, Lu-Ping Yu, Tie-Ming Yu, Wen-Bo Li, Wei-Wei Hu, Xian-Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(9)H(10)N(2)O(2)·H(2)O, the mol­ecular skeleton of the acetohydrazide mol­ecule is nearly planar [within 0.014 (1) Å]. The mol­ecule adopts a trans configuration with respect to the C=N bond, while the side chain is slightly twisted away from the attached ring, forming a dihedral angle of 9.975 (8)°. The crystal packing exhibits a three-dimensional network composed from alternating acetohydrazide mol­ecules and uncoordinated water mol­ecules, which inter­act via N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds. A C—H⋯π inter­action is also present. International Union of Crystallography 2009-07-29 /pmc/articles/PMC2977428/ /pubmed/21583678 http://dx.doi.org/10.1107/S160053680902892X Text en © Lv et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lv, Lu-Ping
Yu, Tie-Ming
Yu, Wen-Bo
Li, Wei-Wei
Hu, Xian-Chao
N′-(4-Hydroxy­benzyl­idene)aceto­hydrazide monohydrate
title N′-(4-Hydroxy­benzyl­idene)aceto­hydrazide monohydrate
title_full N′-(4-Hydroxy­benzyl­idene)aceto­hydrazide monohydrate
title_fullStr N′-(4-Hydroxy­benzyl­idene)aceto­hydrazide monohydrate
title_full_unstemmed N′-(4-Hydroxy­benzyl­idene)aceto­hydrazide monohydrate
title_short N′-(4-Hydroxy­benzyl­idene)aceto­hydrazide monohydrate
title_sort n′-(4-hydroxy­benzyl­idene)aceto­hydrazide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977428/
https://www.ncbi.nlm.nih.gov/pubmed/21583678
http://dx.doi.org/10.1107/S160053680902892X
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