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(μ-Pyridine-2-carbaldehyde azine)bis[bis(triphenylphosphine-κP)copper(I)] bis(tetrafluoridoborate) dichloromethane disolvate
In the centrosymmetric title complex, [Cu(2)(C(12)H(10)N(4))(C(18)H(15)P)(4)](BF(4))(2)·2CH(2)Cl(2), the Cu(I) atom adopts a distorted tetrahedral geometry, defined by two P atoms from two triphenylphosphine ligands and two N atoms from a pyridine-2-carbaldehyde azine ligand. The two Cu atoms are...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977430/ https://www.ncbi.nlm.nih.gov/pubmed/21583313 http://dx.doi.org/10.1107/S160053680902995X |
Sumario: | In the centrosymmetric title complex, [Cu(2)(C(12)H(10)N(4))(C(18)H(15)P)(4)](BF(4))(2)·2CH(2)Cl(2), the Cu(I) atom adopts a distorted tetrahedral geometry, defined by two P atoms from two triphenylphosphine ligands and two N atoms from a pyridine-2-carbaldehyde azine ligand. The two Cu atoms are bridged by the centrosymmetric pyridine-2-carbaldehyde azine ligand. The F atoms of the tetrafluoridoborate anion are disordered over two sites [occupancy factors = 0.68 (5) and 0.32 (5)]. The dichloromethane solvent molecule is disordered over four sites, with occupancy factors of 0.513 (4), 0.173 (5), 0.141 (5) and 0.173 (5). |
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