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(μ-Pyridine-2-carbaldehyde azine)bis­[bis­(triphenyl­phosphine-κP)copper(I)] bis­(tetra­fluorido­borate) dichloro­methane disolvate

In the centrosymmetric title complex, [Cu(2)(C(12)H(10)N(4))(C(18)H(15)P)(4)](BF(4))(2)·2CH(2)Cl(2), the Cu(I) atom adopts a distorted tetra­hedral geometry, defined by two P atoms from two triphenyl­phosphine ligands and two N atoms from a pyridine-2-carbaldehyde azine ligand. The two Cu atoms are...

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Detalles Bibliográficos
Autores principales: Yang, Li, Xie, Yu, Zou, Jianping, Jia, Jie, Hong, Xiaowei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977430/
https://www.ncbi.nlm.nih.gov/pubmed/21583313
http://dx.doi.org/10.1107/S160053680902995X
Descripción
Sumario:In the centrosymmetric title complex, [Cu(2)(C(12)H(10)N(4))(C(18)H(15)P)(4)](BF(4))(2)·2CH(2)Cl(2), the Cu(I) atom adopts a distorted tetra­hedral geometry, defined by two P atoms from two triphenyl­phosphine ligands and two N atoms from a pyridine-2-carbaldehyde azine ligand. The two Cu atoms are bridged by the centrosymmetric pyridine-2-carbaldehyde azine ligand. The F atoms of the tetra­fluorido­borate anion are disordered over two sites [occupancy factors = 0.68 (5) and 0.32 (5)]. The dichloro­methane solvent mol­ecule is disordered over four sites, with occupancy factors of 0.513 (4), 0.173 (5), 0.141 (5) and 0.173 (5).