(μ-Pyridine-2-carbaldehyde azine)bis­[bis­(triphenyl­phosphine-κP)copper(I)] bis­(tetra­fluorido­borate) dichloro­methane disolvate

In the centrosymmetric title complex, [Cu(2)(C(12)H(10)N(4))(C(18)H(15)P)(4)](BF(4))(2)·2CH(2)Cl(2), the Cu(I) atom adopts a distorted tetra­hedral geometry, defined by two P atoms from two triphenyl­phosphine ligands and two N atoms from a pyridine-2-carbaldehyde azine ligand. The two Cu atoms are...

Descripción completa

Detalles Bibliográficos
Autores principales: Yang, Li, Xie, Yu, Zou, Jianping, Jia, Jie, Hong, Xiaowei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977430/
https://www.ncbi.nlm.nih.gov/pubmed/21583313
http://dx.doi.org/10.1107/S160053680902995X
_version_ 1782191106346188800
author Yang, Li
Xie, Yu
Zou, Jianping
Jia, Jie
Hong, Xiaowei
author_facet Yang, Li
Xie, Yu
Zou, Jianping
Jia, Jie
Hong, Xiaowei
author_sort Yang, Li
collection PubMed
description In the centrosymmetric title complex, [Cu(2)(C(12)H(10)N(4))(C(18)H(15)P)(4)](BF(4))(2)·2CH(2)Cl(2), the Cu(I) atom adopts a distorted tetra­hedral geometry, defined by two P atoms from two triphenyl­phosphine ligands and two N atoms from a pyridine-2-carbaldehyde azine ligand. The two Cu atoms are bridged by the centrosymmetric pyridine-2-carbaldehyde azine ligand. The F atoms of the tetra­fluorido­borate anion are disordered over two sites [occupancy factors = 0.68 (5) and 0.32 (5)]. The dichloro­methane solvent mol­ecule is disordered over four sites, with occupancy factors of 0.513 (4), 0.173 (5), 0.141 (5) and 0.173 (5).
format Text
id pubmed-2977430
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29774302010-12-30 (μ-Pyridine-2-carbaldehyde azine)bis­[bis­(triphenyl­phosphine-κP)copper(I)] bis­(tetra­fluorido­borate) dichloro­methane disolvate Yang, Li Xie, Yu Zou, Jianping Jia, Jie Hong, Xiaowei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title complex, [Cu(2)(C(12)H(10)N(4))(C(18)H(15)P)(4)](BF(4))(2)·2CH(2)Cl(2), the Cu(I) atom adopts a distorted tetra­hedral geometry, defined by two P atoms from two triphenyl­phosphine ligands and two N atoms from a pyridine-2-carbaldehyde azine ligand. The two Cu atoms are bridged by the centrosymmetric pyridine-2-carbaldehyde azine ligand. The F atoms of the tetra­fluorido­borate anion are disordered over two sites [occupancy factors = 0.68 (5) and 0.32 (5)]. The dichloro­methane solvent mol­ecule is disordered over four sites, with occupancy factors of 0.513 (4), 0.173 (5), 0.141 (5) and 0.173 (5). International Union of Crystallography 2009-07-31 /pmc/articles/PMC2977430/ /pubmed/21583313 http://dx.doi.org/10.1107/S160053680902995X Text en © Yang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Li
Xie, Yu
Zou, Jianping
Jia, Jie
Hong, Xiaowei
(μ-Pyridine-2-carbaldehyde azine)bis­[bis­(triphenyl­phosphine-κP)copper(I)] bis­(tetra­fluorido­borate) dichloro­methane disolvate
title (μ-Pyridine-2-carbaldehyde azine)bis­[bis­(triphenyl­phosphine-κP)copper(I)] bis­(tetra­fluorido­borate) dichloro­methane disolvate
title_full (μ-Pyridine-2-carbaldehyde azine)bis­[bis­(triphenyl­phosphine-κP)copper(I)] bis­(tetra­fluorido­borate) dichloro­methane disolvate
title_fullStr (μ-Pyridine-2-carbaldehyde azine)bis­[bis­(triphenyl­phosphine-κP)copper(I)] bis­(tetra­fluorido­borate) dichloro­methane disolvate
title_full_unstemmed (μ-Pyridine-2-carbaldehyde azine)bis­[bis­(triphenyl­phosphine-κP)copper(I)] bis­(tetra­fluorido­borate) dichloro­methane disolvate
title_short (μ-Pyridine-2-carbaldehyde azine)bis­[bis­(triphenyl­phosphine-κP)copper(I)] bis­(tetra­fluorido­borate) dichloro­methane disolvate
title_sort (μ-pyridine-2-carbaldehyde azine)bis­[bis­(triphenyl­phosphine-κp)copper(i)] bis­(tetra­fluorido­borate) dichloro­methane disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977430/
https://www.ncbi.nlm.nih.gov/pubmed/21583313
http://dx.doi.org/10.1107/S160053680902995X
work_keys_str_mv AT yangli mpyridine2carbaldehydeazinebisbistriphenylphosphinekpcopperibistetrafluoridoboratedichloromethanedisolvate
AT xieyu mpyridine2carbaldehydeazinebisbistriphenylphosphinekpcopperibistetrafluoridoboratedichloromethanedisolvate
AT zoujianping mpyridine2carbaldehydeazinebisbistriphenylphosphinekpcopperibistetrafluoridoboratedichloromethanedisolvate
AT jiajie mpyridine2carbaldehydeazinebisbistriphenylphosphinekpcopperibistetrafluoridoboratedichloromethanedisolvate
AT hongxiaowei mpyridine2carbaldehydeazinebisbistriphenylphosphinekpcopperibistetrafluoridoboratedichloromethanedisolvate

Ejemplares similares